Cathode & Anode: Explaining the Difference

In summary, in a cathode ray discharge tube, the cathode is the negative electrode and the anode is the positive electrode. However, in a direct current circuit, the anode is the positively charged terminal and the cathode is the negatively charged terminal. This is because current flows away from the cathode, which is why it is connected to the negative pole of the power source. In a voltaic cell, current also flows away from the cathode, making it the positive pole of the cell. This confusion originated from the arbitrary assignment of positive and negative charges during the study of static electricity.
  • #1
WMDhamnekar
MHB
376
28
Hello,

In cathode ray discharge tube,negative electrode is cathode and positive electrode is anode.

But in case of direct current circuit, it is the positively charged terminal of a voltaic cell or storage battery that supplies current and anode is the negatively charged terminal of a voltaic cell or storage battery that supplies current.

Why?
 
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  • #2
It can indeed be a bit confusing and it's a matter of the definition.

Current (positive charge) flows away from the cathode into the electrical circuit.
Mnemonic is CCD: Cathode Current Departs.
Of course in practice we have negative electrons that are the carriers of charge.
And while current flows away from the cathode, equivalently negative electrons flow into the cathode.

It means that for a CRT, we connect the cathode to the negative pole of our power source.
Note that the cathode itself is not the negative pole.
Consequently positive charge flows from the cathode into the power source.
Equivalently, negative electrons flow from the negative pole of the power source into the cathode where they are spit out and fly into the tube.

View attachment 9585

In a voltaic cell, current flows again away from the cathode.
Consequently the cathode itself is the plus pole of the voltaic cell.
Equivalently, the negative electrons flow from the electrical circuit into the cathode where the electrons bind to positive metal ions in the solution.

View attachment 9584
 

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  • #3
You can blame Benjamin Franklin and others of that time! When initially studying static electricity and the way it moves from one place to anther (strictly speaking they weren't working with current then) they arbitrarily assigned "positive" to one pole and "negative" to the other. They did not know that it was the negatively charged electron that carried the current and got the assignment backwards.
 

1. What is the difference between a cathode and anode?

A cathode is the electrode where electrons flow out of a device, while an anode is the electrode where electrons flow into a device. This means that the cathode is the negative terminal and the anode is the positive terminal in a circuit.

2. How do cathodes and anodes work in batteries?

In a battery, the cathode is made of a material that can easily give up electrons, while the anode is made of a material that can easily accept electrons. This creates a flow of electrons from the cathode to the anode, producing an electric current.

3. Can the roles of cathodes and anodes be reversed?

Yes, in certain devices such as diodes, the roles of cathode and anode can be reversed. In these devices, the flow of electrons is controlled by the direction of the current, rather than the materials used for the electrodes.

4. What are some common examples of cathodes and anodes?

Cathodes are commonly made of materials such as copper, silver, or graphite, while anodes are often made of materials like zinc, aluminum, or lithium. These materials are used in various devices such as batteries, electrolytic cells, and vacuum tubes.

5. How do cathodes and anodes contribute to corrosion in metals?

In a process called galvanic corrosion, the anode of a metal will corrode faster than the cathode when exposed to an electrolyte, such as saltwater. This is because the anode is the site where electrons are released, leading to the breakdown of the metal. This can be prevented by using a sacrificial anode, where a more reactive metal is used as the anode to protect the less reactive metal.

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