Do you mean the group generated by i, j, k, where i^2 = j^2 = k^2 = i*j*k = -1?
One can easily derive i*j = - j*i = k, j*k = - k*j = i, k*i = - i*k = j
Its elements are {1,-1,i,-i,j,-j,k,-k}, 8 of them
Its conjugacy classes are {1}, {-1}, {i,-i}, and likewise for j and k.
Its nontrivial subgroups are {1,-1}, {1,i,-1,-i}, and likewise for j and k.
All of them are normal; they have quotient groups Z2*Z2, and 3 Z2's.
Since it has 8 elements, it is thus a subgroup of S8. Multiplying by an element -> creating a permutation of elements. Since all the multiplication permutations are even, this group is also a subgroup of A8.
I tried to find out whether it is also a subgroup of S4, S5, S6, or S7 -- as far as I can tell, it isn't. I did that by looking for order-4 elements, finding which pairs of them have an order-4 product, and which pairs a, b of them have a*b*a*b = b*a*b*a. There are some for S8, but not for S7 or smaller index.
So one has to look for a degree-8 polynomial to find one with the quaternion group as the Galois group.