Describe the methods of classifying polymeric materials

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In summary, the conversation discusses the various ways in which polymers can be classified, including in terms of commercial and industrial use, physical form, and material structure. Different types of polymers, such as thermoplastics, rubbers, and textiles, are also mentioned and their properties are described. The conversation also touches on the increasing variety and complexity of polymer materials in modern times.
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Tiberious
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Homework Statement



Can anyone advise if this is a satisfactory answer. I've had a run over it and it does seem rather bulky for the given question.

The Attempt at a Solution



Commercial and marketing:

Polymers can be classified in a variety of different ways. The commercial market are enticed by the use of polymers because of the general affordability of the raw material, the ease of mass market manufacture such as tooth brushes, toothpaste tubes, ear bud sticks etc. The polymers produced are commonly for ‘one-use’ applications, this leads to a continuous stream of revenue for the manufacturer.

Industrial design and application:

Another method of classification is for the industrial design and application market. Once the raw materials for thermoplastic or thermoset plastics have been heated designers can use injection mounding techniques to create shapes that would be difficult to obtain by ordinary secondary finishing techniques.

Physical form of component:

Polymeric materials can be defined In terms of physical form into the below six groups.

Plastics

Thermosetting plastics – Once initially heated the thermosetting plastic shares thermoplastic properties, however, once the plastic has solidified and cooled sufficiently it becomes resistant to heat. Once a sufficient amount of heat has been applied to the resultant product it will thermally decompose.

Thermoplastics – Once a thermoplastic has cooled it can be re-heated to the glass transition temperature , after reaching this point the material will soften and become malleable ready for repurposing (reuse).

Rubbers

Rubber can be defined as natural rubber (NR) or synthetic rubber (SBR) or (CR). Rubber are most commonly used in the ‘cured’ or ‘vulcanised’ form. This is where the rubber molecules have formed chemical cross links to other rubber molecules. The resultant being a three dimensional open molecular network.

Textile Fibres

Natural fibres – Most commonly used in fabrics, ropes and twines.

Synthetic fibres - Thermoplastic in origin. These spun and weaved into threads.
Adhesives + Coatings

Either natural or man-made. Adhesives and coatings can come from any of the previously mentioned ‘types’. The materials can be a designed combination of all different polymeric materials. Such as PF, epoxy resin, NR and combinations of the same.

Composite Materials

Composites are designed combinations of polymeric materials and other constituents such as glass fibre. These provide different properties that can be applied to various different situations.

Material Structure:

Amorphous Thermoplastics

These have branched polymer molecules that do not crystallise into a solid configuration. Thus, having no crystalline melting point . However, they have various ‘softening’ points, including

Low-Crystallinity Thermoplastics

Mostly consisting of PVC polymers. Fitting between the amorphous and crystalline thermoplastics. They also have the softening points of However, they also have a melting transition at .

Crystalline Thermoplastics

Whilst in the crystalline state, the polymer chains have a higher visco-elastic mannerism. Textile fibres would be included in this Crystalline Thermoplastics section.

Thermosetting polymers

The tri-dimensional molecules produced during the forming and curing prohibit crystallisation. Such materials do not poses a melting point . or a softening point thus are normally brittle.

Rubbery Materials.

Firstly being amorphous thermoplastics, they transition to rubbery materials once vulcanised/cured this giving the polymer the very flexible, open and interconnected network of molecules. Thus the material assumes it’s rubbery properties.
 
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  • #2
Tiberious said:
rather bulky for the given question.
It's a "rather bulky bulky" material properties area, and growing bulkier by the day/minute/hour (rapidly). Compare the variety of today to that of a century ago, and how many orders of magnitude are we discussing?
 

What are polymeric materials?

Polymeric materials are large molecules made up of repeating units called monomers. They are commonly found in everyday objects such as plastics, rubber, and synthetic fibers.

Why is classification of polymeric materials important?

Classification of polymeric materials allows scientists and engineers to understand the properties and behaviors of different materials, which can help in selecting the most suitable material for a specific application. It also aids in the development of new materials with desired properties.

What are the different methods of classifying polymeric materials?

The main methods of classification include chemical structure, molecular weight, and physical properties. Chemical structure involves identifying the types of monomers present in the polymer, while molecular weight refers to the size and distribution of the polymer chains. Physical properties, such as melting point and solubility, can also be used to classify polymers.

How is chemical structure used in classifying polymeric materials?

Chemical structure is used to classify polymers based on the types of monomers present and the bonding between them. Polymers can be classified as homopolymers, copolymers, or terpolymers based on the number and types of monomers. They can also be classified as linear, branched, or cross-linked depending on the type of bonding between monomers.

Can a polymer belong to multiple classification categories?

Yes, a polymer can belong to multiple classification categories. For example, a polymer can be a copolymer with both homopolymer and terpolymer characteristics, or it can have both linear and branched structures. This is because polymers can have complex structures and properties that cannot be solely defined by one classification method.

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