Energy differences of molecular orbitals

AI Thread Summary
The discussion centers on comparing the energy levels of molecular orbitals, specifically the 1s antibonding orbital and the 2s bonding orbital in molecules A-A and A-B. It is established that antibonding orbitals are generally higher in energy than bonding orbitals. The construction of molecular orbital (MO) diagrams is emphasized, with the skill being taught in inorganic chemistry courses. A point of confusion arises regarding the energy levels, with one participant initially asserting that the 1s antibonding orbital is higher in energy than the 2s bonding orbital. However, this claim is later corrected, referencing a textbook that states for homonuclear diatomic molecules from hydrogen to neon, the 2s-2s bonding orbitals are indeed higher in energy than the 1s-1s antibonding orbitals.
Helena Wells
Messages
125
Reaction score
9
Suppose we have a molecule A-A and a molecule A-B . And we want to compare the differences in energy of the different molecular orbitals for example the 1s antibonding orbital with the 2s bonding orbital.How can we do that?
 
Last edited:
Chemistry news on Phys.org
Antibonding orbitals are higher in energy than bonding orbitals. you can construct MO diagrams by following certain rules. at my university the skill is taught in inorganic chemistry
 
  • Skeptical
Likes Helena Wells
docnet said:
Antibonding orbitals are higher in energy than bonding orbitals. you can construct MO diagrams by following certain rules. at my university the skill is taught in inorganic chemistry
I don't think that is true . Are you saying the 1s antibonding orbital has higher energy than the 2s bonding orbital?
 
Helena Wells said:
I don't think that is true . Are you saying the 1s antibonding orbital has higher energy than the 2s bonding orbital?
I was mistaken. Now I don't think the question makes any sense.
 
Here you go. My textbook says 2s-2s bonding orbitals are higher in energy than the 1s-1s antibonding orbitals for homonuclear diatomiicc molecules of the first 10 elements, from H to Ne.
Screen Shot 2021-02-21 at 5.52.43 PM.png
 

Attachments

I want to test a humidity sensor with one or more saturated salt solutions. The table salt that I have on hand contains one of two anticaking agents, calcium silicate or sodium aluminosilicate. Will the presence of either of these additives (or iodine for that matter) significantly affect the equilibrium humidity? I searched and all the how-to-do-it guides did not address this question. One research paper I found reported that at 1.5% w/w calcium silicate increased the deliquescent point by...
I was introduced to the Octet Rule recently and make me wonder, why does 8 valence electrons or a full p orbital always make an element inert? What is so special with a full p orbital? Like take Calcium for an example, its outer orbital is filled but its only the s orbital thats filled so its still reactive not so much as the Alkaline metals but still pretty reactive. Can someone explain it to me? Thanks!!
I'm trying to find a cheap DIY method to etch holes of various shapes through 0.3mm Aluminium sheet using 5-10% Sodium Hydroxide. The idea is to apply a resist to the Aluminium then selectively ablate it off using a diode laser cutter and then dissolve away the Aluminium using Sodium Hydroxide. By cheap I mean resists costing say £20 in small quantities. The Internet has suggested various resists to try including... Enamel paint (only survived seconds in the NaOH!) Acrylic paint (only...
Back
Top