First and Second Law of Thermodynamics

In summary, we discussed the process of an ideal gas confined within a thermally isolated cylinder, where a given amount of heat Q is slowly added to the gas and a movable piston allows the gas to expand while maintaining a constant temperature. We also explored the concept of internal energy and how it remains constant in this process due to the ideal gas law. We also considered the second law of thermodynamics and how it affects the conversion of heat into work done by the piston. Finally, we determined that the total work done by the gas is independent of the area of the piston.
  • #1
Soaring Crane
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An ideal gas is confined within a thermally isolated cylinder. It consists of N atoms initially at a pressure of p_0. A movable piston seals the right end of the cylinder. A given amount of heat Q is slowly added to the gas, while the piston allows the gas to expand in such a way that the gas's temperature remains constant at T_0.

Is the internal energy of the gas the same before and after Q is added?
Is this true since it has to follow the law of the conservation of energy?

Does the second law of thermodynamics forbid converting all of the absorbed heat Q into work done by the piston?
Is the movable piston a cycle? I think it is, so it must follow the second law?

Is the total work done by the gas independent of the area of the piston?

Well, the total work is dW = p*dV, and since V = A*h, then work is dependent and not independent?
 
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  • #2
Soaring Crane said:
An ideal gas is confined within a thermally isolated cylinder. It consists of N atoms initially at a pressure of p_0. A movable piston seals the right end of the cylinder. A given amount of heat Q is slowly added to the gas, while the piston allows the gas to expand in such a way that the gas's temperature remains constant at T_0.

Is the internal energy of the gas the same before and after Q is added?
Is this true since it has to follow the law of the conservation of energy?

What does James Prescott Joule's experiment tell u about ideal gases...??

Soaring Crane said:
Does the second law of thermodynamics forbid converting all of the absorbed heat Q into work done by the piston?
Is the movable piston a cycle?

What??What kind of the process is described in the problem...?

Soaring Crane said:
Is the total work done by the gas independent of the area of the piston?

Well, the total work is dW = p*dV, and since V = A*h, then work is dependent and not independent?

Think again...What is changing in the volume...??The area or the "length" of the tube (improperly said)?

Daniel.
 
  • #3
Soaring Crane said:
An ideal gas is confined within a thermally isolated cylinder. It consists of N atoms initially at a pressure of p_0. A movable piston seals the right end of the cylinder. A given amount of heat Q is slowly added to the gas, while the piston allows the gas to expand in such a way that the gas's temperature remains constant at T_0.

Is the internal energy of the gas the same before and after Q is added?
Is this true since it has to follow the law of the conservation of energy?
Use the Ideal gas law: PV=nRT = internal energy of the gas. If T and n do not change then PV cannot change. (Since V increases, P must decrease as 1/V).

Does the second law of thermodynamics forbid converting all of the absorbed heat Q into work done by the piston?
Is the movable piston a cycle? I think it is, so it must follow the second law?
This is an interesting question. Since the container is thermally isolated, no heat can escape. The first law says that [itex]\Delta Q = \Delta U + \Delta W[/itex]. Since [itex]\Delta U = \Delta PV = nR\Delta T = 0[/itex] in this process, it would appear that [itex]\Delta Q = \Delta W[/itex] where [itex]\Delta W[/itex] is the work done by the system. Since this would violate the second law, we can conclude that this is not the entire system. I think the second law tells us that there had to be an external source of energy, in addition to the added heat, to move the piston and expand the gas. The heat alone could not do the work of moving the piston.

Is the total work done by the gas independent of the area of the piston?

Well, the total work is dW = p*dV, and since V = A*h, then work is dependent and not independent?
I don't think so. The total work done by the gas is:

[tex]\int_{V_i}^{V_f} PdV = \int_{V_i}^{V_f} \frac{dV}{V} = ln(\frac{V_i}{V_f})[/tex]

It is independent of the area of the piston.

AM
 
  • #4
Soaring Crane said:
Is the total work done by the gas independent of the area of the piston?

Well, the total work is dW = p*dV, and since V = A*h, then work is dependent and not independent?

While it is true that V = A*h, it is also true that p = F/A. So the A's cancel each other out and the work done is therefore independent of the area. :smile:
 

Related to First and Second Law of Thermodynamics

What is the First Law of Thermodynamics?

The First Law of Thermodynamics, also known as the Law of Conservation of Energy, states that energy cannot be created or destroyed, it can only be transferred or converted from one form to another.

What is the Second Law of Thermodynamics?

The Second Law of Thermodynamics states that in any energy transfer or conversion, some energy will inevitably be wasted and lost as heat. This means that the total amount of usable energy in a closed system will decrease over time.

How do the First and Second Laws of Thermodynamics relate to each other?

The First Law of Thermodynamics tells us that energy is conserved, while the Second Law tells us that energy will always move from a more usable form to a less usable form. In other words, the First Law allows us to track energy as it changes forms, while the Second Law explains why energy cannot be converted without any losses.

What is an example of the First Law in action?

One example of the First Law in action is a light bulb. When electricity flows through the filament of a light bulb, it converts the electrical energy into light and heat energy. This shows that energy is conserved, as the total amount of energy before and after the conversion remains the same.

What is an example of the Second Law in action?

An example of the Second Law of Thermodynamics is a car engine. As the fuel is burned and converted into mechanical energy to move the car, some energy is lost as heat due to friction. This loss of energy is irreversible, and as a result, the total amount of usable energy in the car's system decreases over time.

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