Fluids: Kistler contact angle model

PFIn summary, the Kistler's contact angle model uses a function f to represent the advancing contact angle and a function f^-1 to represent the receding contact angle. This is why the left side of the plot has a different shape than the right side. To generate the left side of the plot, the receding contact angle function should be used instead of the advancing contact angle function.
  • #1
member 428835
Hi PF!

I keep seeing Kistler's contact angle model wrote like this $$ \theta_d = f(Ca+f^{-1}(\theta_e)) : f = \arccos\left( 1-2\tanh\left( 5.15 \left( \frac{x}{1+1.31x^{0.99}} \right)^{0.706} \right) \right) $$, where the plot then has a sort of break, something like this:
model.png

But this is not the above function, as it only works for advancing contact lines (right half of plot). How is the left side generated?
 
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  • #2


Hi there!

The left side of the plot is generated using the receding contact angle, which is the angle formed between the liquid and the solid surface when the liquid is receding from the solid surface. This angle is typically smaller than the advancing contact angle, as the liquid is pulling away from the surface instead of advancing towards it.

In Kistler's contact angle model, the function f represents the advancing contact angle, while the function f^-1 represents the receding contact angle. This is why the left side of the plot has a different shape than the right side. To generate the left side of the plot, you would need to use the receding contact angle function instead of the advancing contact angle function.

I hope this helps clarify the plot for you. Let me know if you have any other questions!

 

1. What is the Kistler contact angle model?

The Kistler contact angle model is a mathematical model used to describe the contact angle of a liquid on a solid surface. It takes into account the surface tension of the liquid, the surface energy of the solid, and the interfacial tension between the two. This model is often used in fluid dynamics and surface science research.

2. How does the Kistler contact angle model work?

The Kistler contact angle model uses the Young-Laplace equation to calculate the contact angle of a liquid on a solid surface. This equation takes into account the surface energies of the liquid and solid, as well as the interfacial tension between them. The model also considers the shape and curvature of the liquid droplet on the surface.

3. What are the key assumptions of the Kistler contact angle model?

The Kistler contact angle model assumes that the liquid and solid surfaces are both flat and smooth, and that the liquid droplet is in thermodynamic equilibrium with its surroundings. It also assumes that there is no evaporation or condensation of the liquid, and that the surface energies and interfacial tension remain constant throughout the process.

4. What are the applications of the Kistler contact angle model?

The Kistler contact angle model has various applications in research and industry. It is commonly used in surface science to study the wetting behavior of liquids on solid surfaces. It is also used in the development of coatings and adhesives, as well as in the design of microfluidic devices and biomedical implants.

5. Are there any limitations to the Kistler contact angle model?

Like any mathematical model, the Kistler contact angle model has its limitations. It assumes ideal conditions and may not accurately predict the contact angle in real-world scenarios where the surfaces are not perfectly flat or the liquid is not in equilibrium. It also does not take into account other factors such as surface roughness or chemical interactions between the liquid and solid surfaces.

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