How did Ludwig Boltzmann develop the Boltzmann distribution and define entropy?

In summary, Boltzmann developed the Boltzmann distribution and the statistical definition of entropy, which applies to classical particles and does not consider the issue of indistinguishability. He also introduced a kinetic equation that takes into account particle collisions and showed that a quantity he called H, related to the entropy of the gas, cannot increase if this equation holds. Despite some sources using discrete energy levels, the states are actually not discrete and this quantity is determined up to an additive constant, similar to entropy in Thermodynamics. Unfortunately, Boltzmann committed suicide.
  • #1
Amok
256
2
So this guy came up with the Boltzmann distribution and the statistical definition of entropy, where particles occupy discrete energy levels (or states) before the advent of quantum mechanics. How the hell did he do that, does anyone have any knowledge on how Boltzmann came up with the stuff he came up with? Or maybe he did not think of the states as being discrete?
 
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  • #2
Probability theory was a well developed mathematical field by the first half of the XIX century. The Boltzmann distribution is characteristic for classical particles for which the issue of indistinguishably is not essential. Boltzmann developed a kinetic equation which treated the collision between the particles for the first time. He also showed that a quantity he called H, and is related to the entropy of the gas, cannot increase if this equation holds. And, as you wondered correctly, the states are not discrete, so this quantity is determined up to an additive constant, just like entropy in Thermodynamics. He committed suicide, btw.
 
  • #3
Ok... I was just wondering about that because most derivations and statements of the Boltzmann distribution found on the net and in books (at least the ones I've come across) use discrete energy levels. Take a look at wikipedia's page on the distribution, for example.
 

Related to How did Ludwig Boltzmann develop the Boltzmann distribution and define entropy?

What is Ludwig Boltzmann best known for?

Ludwig Boltzmann was a physicist and mathematician who is best known for his contributions to the development of statistical mechanics. He is also known for his work on the kinetic theory of gases and the Boltzmann equation.

What is the Boltzmann constant and how is it used?

The Boltzmann constant, denoted by k, is a fundamental physical constant that relates the average kinetic energy of particles in a gas to its temperature. It is used in many equations in thermodynamics and statistical mechanics, such as the ideal gas law and the Maxwell-Boltzmann distribution.

What is the significance of Boltzmann's entropy formula?

Boltzmann's entropy formula, also known as the Boltzmann's H-theorem, is a mathematical expression that describes the tendency of a system to move towards equilibrium and to increase in disorder or entropy. It is a fundamental concept in statistical mechanics and has applications in various fields, including chemistry, physics, and biology.

What are Boltzmann's contributions to the development of quantum mechanics?

Boltzmann's work on statistical mechanics played a crucial role in the development of quantum mechanics. He used statistical methods to explain the behavior of particles at the atomic and subatomic level, which eventually led to the development of quantum mechanics. His work also influenced the development of the uncertainty principle and the quantum theory of radiation.

What is Boltzmann's legacy in the field of physics?

Boltzmann's work has had a lasting impact on the field of physics and continues to influence research and theories today. His contributions to statistical mechanics and thermodynamics are essential to our understanding of the behavior of matter and energy. He is also credited with laying the foundations for the study of complex systems and the development of chaos theory.

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