Localized surface plasmon resonance (LSPR)

In summary, localized surface plasmon resonance (LSPR) is a phenomenon where light interacts with metallic nanoparticles, causing the electrons on their surface to oscillate and absorb light at a specific wavelength. This is due to the interaction between light and free electrons on the surface of the particles. LSPR has various applications in fields such as biosensing, medical diagnostics, and optoelectronics. It can be observed in different materials, but metallic nanoparticles are the most commonly used. LSPR can be measured using techniques such as UV-Vis spectroscopy, surface plasmon resonance (SPR) spectroscopy, and dark-field microscopy.
  • #1
paulzhen
33
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Hi!

I wondering does anyone here has a clue of lowering the absorption level and narrowing the scattering bandwidth of LSPR of nanoparticles? Are those "intrinsic" properties or can be improved by modifying their size, shapes, etc?

Thanks for sharing your thoughts!

Paul
 
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  • #2


Hi Paul,

Thank you for your question! Lowering the absorption level and narrowing the scattering bandwidth of localized surface plasmon resonance (LSPR) of nanoparticles can be achieved through various methods. These properties are considered "intrinsic" to the nanoparticles, as they are determined by their composition and size.

One way to lower the absorption level of LSPR is to use materials with lower extinction coefficients, such as silver or gold, which have strong LSPR signals. Additionally, the size and shape of the nanoparticles can also affect the absorption level. For example, smaller nanoparticles with a higher surface-to-volume ratio will have a stronger LSPR signal compared to larger nanoparticles.

To narrow the scattering bandwidth of LSPR, the shape of the nanoparticles can be modified. For instance, using elongated or rod-shaped nanoparticles rather than spherical ones can result in a narrower scattering bandwidth.

Furthermore, surface modifications can also play a role in controlling the LSPR properties of nanoparticles. By functionalizing the surface of the nanoparticles with different molecules, the LSPR signal can be tuned to specific wavelengths and the scattering bandwidth can be narrowed.

In summary, the absorption level and scattering bandwidth of LSPR can be improved by modifying the size, shape, and surface properties of the nanoparticles. I hope this helps answer your question. Let me know if you have any further inquiries.

 

What is localized surface plasmon resonance (LSPR)?

Localized surface plasmon resonance (LSPR) is a phenomenon that occurs when light interacts with metallic nanoparticles, causing the electrons on the surface of the particles to oscillate in a collective motion. This results in a strong absorption of light at a specific wavelength, known as the plasmon resonance peak.

How does LSPR work?

LSPR is a result of the interaction between light and free electrons on the surface of metallic nanoparticles. When a light wave hits a nanoparticle, the electrons on the surface of the particle are excited and begin to oscillate in response to the electric field of the light. This collective oscillation of electrons creates a strong absorption of light at a specific wavelength, leading to the plasmon resonance peak.

What are the applications of LSPR?

LSPR has a wide range of applications in various fields, including biosensing, medical diagnostics, and environmental monitoring. It has also been used in the development of new materials for optoelectronics, photovoltaics, and catalysis.

What types of materials can exhibit LSPR?

LSPR can be observed in various materials, including noble metals such as gold, silver, and copper, as well as other materials like semiconductors, oxides, and polymers. However, metallic nanoparticles are the most commonly used materials for LSPR due to their strong interaction with light.

How is LSPR measured?

LSPR can be measured using various techniques, including UV-Vis spectroscopy, surface plasmon resonance (SPR) spectroscopy, and dark-field microscopy. These techniques measure the absorption, scattering, and extinction of light by the nanoparticles, which can then be used to determine the plasmon resonance peak and other characteristics of the LSPR phenomenon.

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