Powder XRD FCC spirals explanation

In summary, the conversation discusses the use of X-ray diffraction (XRD) in determining the lattice parameter of an FCC lattice. The speaker also questions the use of spirals in calculating the lattice parameter and suggests that computers may now be able to do so without visual aids. The response clarifies that the spirals are used to find the polar angle where the experimental data crosses, indicating the lattice parameter, and that the distance from different planes changes as the polar angle increases. The use of spirals comes from spanning the lattice constant.
  • #1
mohammed.omar
32
0
Hello All,

I've been reading about XRD and found this picture online:
http://en.wikipedia.org/wiki/File:Aluminumpowderpattern.png

My question, which might be due to the lack of background as I'm an ECE guy, is why are the FCC lattice vectors depicted of Spirals whose minima lie on the vertical axis?
 
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  • #2
The spirals are calculated to help find the lattice parameter of the sample under investigation.

The lattice parameter of the FCC lattice is changed as function of the polar angle. You look for the polar angle where the experimental data (circles, not spirals) cross the spirals - hopefully all at once. In the image this is indicated by the blue line.

I would think that these days a computer is able to find lattice parameters without such visual aids. But the papers cited are surprisingly recent.
 
  • #3
Thanks M Quack,

So as the polar angle is increased the distance from the different planes changes and that is why we get a Spiral? If tihs is the case then why do they all have minima at the vertical axis?
 
  • #4
Or these spirals just come from spanning the lattice constant?
 
  • #5
spanning the lattice constant.
 
  • #6
Thanks a lot M Quack
 

What is Powder XRD FCC spirals explanation?

Powder X-ray diffraction (XRD) is a commonly used analytical technique in materials science to determine the structure of crystalline materials. The FCC spirals explanation refers to the analysis of the diffraction patterns of materials with a face-centered cubic (FCC) crystal structure.

Why is Powder XRD FCC spirals explanation important?

Powder XRD FCC spirals explanation is important because it provides information about the crystal structure of a material, which is crucial for understanding its physical and chemical properties. This information can be used to identify unknown materials, determine their purity, and monitor phase changes during synthesis or processing.

How does Powder XRD FCC spirals explanation work?

In Powder XRD FCC spirals explanation, a sample is bombarded with a beam of X-rays. The X-rays interact with the atoms in the sample, causing them to diffract or scatter in different directions. These scattered X-rays form a diffraction pattern, which can be analyzed to determine the crystal structure of the material.

What are the limitations of Powder XRD FCC spirals explanation?

Although Powder XRD FCC spirals explanation is a powerful tool for characterizing materials, it does have some limitations. For example, it cannot be used for amorphous materials (lack of long-range order), and it is not suitable for studying materials with very small crystal sizes (nanomaterials).

What are some applications of Powder XRD FCC spirals explanation?

Powder XRD FCC spirals explanation has a wide range of applications in materials science, including pharmaceuticals, ceramics, metals, and minerals. It is used for phase identification, crystallite size determination, and quantification of different phases in a sample. It is also used in quality control and process monitoring in industries such as pharmaceuticals and semiconductors.

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