Problem about electronic structure

In summary, the discussion revolved around the electronic structure of carbon nanotubes (CNT) and its relation to the band structure of graphene. While CNTs are considered to be one-dimensional structures due to their macroscopic axial direction, they also have quantized circumferential states which allow for transitions between them. This results in a movement that is two-dimensional, but CNTs are still classified as 1D structures due to the high energy excitations in the circumferential direction.
  • #1
davidpotter
5
0
Hello everyone!
The electronic structure of CNT is discussed on the basis of band structure of graphene. Graphene has a linear dispersion relation: E = h_cut vF |k| where k is the 2D wavevector and vF is the Fermi velocity. CNTs are macroscopic along the axis but have a circumference of atomic dimensions, which suggests that there will be large states in the axial direction but quantized circumferential states. this implies that there are allowed transitions between circumferential states such that the movement is in the direction perpendicular to the axial direction of CNT. Therefore the movement is in two dimensions, yet we say CNT is a 1D structure. Why is that the case?
 
  • #3
There are no truly one dimensional structures in nature, so this always has to be understood as kind of an approximation. Namely, if the radius of the CNT (I suppose you mean carbon nanotubes -- if you expect an answer, it would be really wise to spell out your abbreviations once) is small, the corresponding excitations will be relatively high energy. So on energy scales small compared to these energies, you will only have to control the motion in one dimension.
 

Related to Problem about electronic structure

What is electronic structure?

Electronic structure refers to the arrangement of electrons within an atom, molecule, or solid material. It determines the chemical and physical properties of a substance.

What is the significance of understanding electronic structure?

Understanding electronic structure is crucial in various fields of science, such as chemistry, physics, and materials science. It allows us to predict and explain the behavior of atoms and molecules, as well as design and develop new materials with specific properties.

What factors affect electronic structure?

The electronic structure of an atom is affected by its atomic number, which determines the number of protons and electrons, as well as the energy levels and sublevels of these electrons. It is also influenced by external factors such as temperature and pressure.

What is the role of electrons in electronic structure?

Electrons play a crucial role in electronic structure as they determine the chemical and physical properties of a substance. They are responsible for chemical bonding and the transfer of energy within a material.

How is electronic structure studied?

Electronic structure is studied through various experimental techniques such as spectroscopy, X-ray crystallography, and electron microscopy. Theoretical models and computer simulations are also used to understand and predict electronic structure.

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