Recombination of ion pairs in an ionization chamber

In summary, in an ionization chamber, the fill gas is ionized by incident radiation and the resulting ion pair moves to the opposite polarity electrode. The positive ion is then consumed in the same circuit as the electron, creating a signal for the operator. Eventually, the ion pair recombines at the surface of the electrode, with the same electron that was produced during ionization. This process does not affect noble gases, but may break up molecules in other gases.
  • #1
bhope691
5
0
What happens to the fill gas in an ionization chamber?

Once incident radiation has created an ion pair, which has then moved to its opposite polarity electrode, is that ion pair removed from the fill gas? So if enough incident radiation is detected over a period of time all the gas would be ionized and a vacuum left in its place?

What then happens to the positive ion? Is it consumed in the same circuit the electron is? (The circuit that produces a representation of the incident radiation for the operator)

If this isn't the case, when does the ion pair recombine whilst still giving an indication to the ionization chamber operator that radiation has been detected?
 
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  • #2
Atoms don't magically disappear. The ion reaches the electrode, picks up an electron (this is part of the signal - you get electrons at one side and the other side needs additional electrons) and becomes an uncharged atom as part of the gas again.
For noble gases, this is identical to the original state of the atom. For other gases, it means you break up molecules of an extremely tiny fraction of the gas. This does not matter - due to leakages, you need some constant gas flow through the detector anyway.
 
  • #3
Thanks mfb,

So for an example using argon; once ionized the Ar+ moves to the negative electrode, is it at the surface of the electrode or 'inside' the electrode that it then recombines with an electron? Is it the same electron that is produced when the Ar is ionized, which it recombines with?
 
  • #4
It happens at the surface.
bhope691 said:
Is it the same electron that is produced when the Ar is ionized, which it recombines with?
Electrons are indistinguishable. And even if they would be distinguishable (to make an answer possible): No.
 

1. What is recombination of ion pairs in an ionization chamber?

Recombination of ion pairs refers to the process in which positive and negative ions that are created through ionization within an ionization chamber recombine to form neutral molecules or atoms. This can occur due to various factors such as the presence of impurities or the recombination of ions with opposite charges.

2. How does recombination of ion pairs affect the accuracy of measurements in an ionization chamber?

The recombination of ion pairs can lead to a decrease in the number of detected ions, resulting in a decrease in the measured ionization current. This can affect the accuracy of measurements in an ionization chamber, particularly at high radiation intensities.

3. What are some methods used to mitigate the effects of recombination in an ionization chamber?

One common method is to use a correction factor based on the recombination coefficient, which is a measure of the probability of ion recombination. Another method is to increase the distance between the electrodes in the ionization chamber to allow more time for ions to drift and recombine before reaching the collecting electrode.

4. What factors can influence the recombination of ion pairs in an ionization chamber?

The presence of impurities, temperature, and the electric field strength within the ionization chamber can all affect the recombination of ion pairs. Additionally, the type of gas and the energy of the incident radiation can also play a role in the recombination process.

5. How can recombination of ion pairs be quantified in an ionization chamber?

The recombination coefficient can be used to quantify the amount of recombination in an ionization chamber. This can be determined experimentally by measuring the ionization current at different radiation intensities and calculating the ratio of the measured current to the expected current based on the number of ion pairs produced.

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