Transmittance and Absorbtion of light

In summary, the conversation discusses the graph attached and attempts to determine whether 'Z' represents the absorptance or transmittance of amorphous silicon or CiGS, or the absorptance of ZnO. It is determined that ZnO has a bandgap of 3.3eV and the graph does not trend upward after this point, ruling out ZnO as the answer. The information found on PVEducation suggests that 'Z' could be the absorptance of CiGs, as it increases around the bandgap energy values of 1.1eV and 1.7eV. It is also noted that the transmittance of CiGs would not be high around these values,
  • #1
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I'm trying to understand the graph (attached) and if 'Z' is the absorptance or transmittance of amorphous silicon or CiGS, or the absorptance of ZnO.

The bandgap of CiGs is between 1.1eV and 1.7eV.

ZnO has a bandgap of 3.3eV, so any photon energy below that will not be absorbed. The 'Z' part of the graph doesn't trend upward after 3.3 either, so I don't think 'Z' is the absorptance of ZnO. That leaves amorphous silicon and CiGs.

I found this info (below) on PVEducation. It makes me think that the answer is the absorptance of CiGs, because 'Z' increases around the 1.1eV and 1.7eV values, and above 1.7eV, the energy of the photon is > energy of the bandgap. It couldn't be the transmittance of CiGs because it wouldn't be so high around 1.1eV to 1.7eV. It would be low, no?
  • Eph < EG Photons with energy Eph less than the band gap energy EG interact only weakly with the semiconductor, passing through it as if it were transparent.
  • Eph = EG have just enough energy to create an electron hole pair and are efficiently absorbed.
  • Eph > EG Photons with energy much greater than the band gap are strongly absorbed. However, for photovoltaic applications, the photon energy greater than the band gap is wasted as electrons quickly thermalize back down to the conduction band edges.
source: http://www.pveducation.org/pvcdrom/pn-junction/absorption-of-light
 

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  • #2
we need more information on how the graphs were obtained, it looks like Z is either the reflectance or transmittance and X is the complement (transmittance or reflectance) and Y is the absorption, they do not indicate on the graph.
 

What is the difference between transmittance and absorption of light?

Transmittance refers to the amount of light that passes through a material without being absorbed. It is typically measured as a percentage, with 100% indicating all light is transmitted and 0% indicating all light is absorbed. Absorption, on the other hand, refers to the process of light being absorbed by a material, resulting in a decrease in the intensity of the light. It is also measured as a percentage, with 100% indicating all light is absorbed and 0% indicating no light is absorbed.

How are transmittance and absorption of light related?

Transmittance and absorption of light are inversely related - as one increases, the other decreases. This means that if a material has a high transmittance, it will have a low absorption and vice versa.

What factors can affect the transmittance and absorption of light?

The transmittance and absorption of light can be affected by several factors, including the wavelength of the light, the thickness and type of material the light is passing through, and the concentration of particles or molecules in the material. Other factors such as temperature and pressure can also play a role in the transmittance and absorption of light.

How is the transmittance and absorption of light measured?

Transmittance and absorption of light are typically measured using a spectrophotometer, which measures the amount of light that passes through a sample at different wavelengths. The results are then used to calculate the transmittance and absorption values.

Why is understanding transmittance and absorption of light important?

Understanding transmittance and absorption of light is crucial in many scientific fields, including chemistry, physics, and biology. It allows us to analyze and quantify the properties of materials, such as their color, transparency, and ability to block or transmit light. This knowledge is also essential in the development of new technologies, such as solar cells and optical fibers, and in environmental studies, such as measuring the concentration of pollutants in air or water.

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