Wave function and orbital question

In summary, the conversation discusses the concept of wave functions in relation to orbitals and their phases. The wave function represents the true form of a particle in the universe and its phase plays a role in determining how the wave will interfere with itself. The phase of the wave function does not have any specific meaning in relation to charge or electron spin. When phases cancel out, they create an antibonding molecular orbital. It is recommended to have a basic understanding of quantum mechanics before studying this concept. There are various resources available for learning quantum physics.
  • #1
f24u7
46
0
Hi, I have a few question about orbitals


1. What does psi or wave function represents?

2. When talking about orbitals what does phases actually mean (does it relate to charge
and electron spin)?

3. What's the mechanic behind when phases cancel out to create
sigma*1s antibonding molecular orbital?
 
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  • #2
1. Probability amplitude

2. example of phase: Sin(x + pi/3), is Sin(x) shifted by phase pi/3

3. not an expert on molecular physics ;-) hope someone else answers
 
  • #3
f24u7 said:
1. What does psi or wave function represents?

The wave function is the true form of a particle in the universe. The magnitude of this complex number at any point is the square root of the probability of detecting the particle at that point. The phase angle of the number just plays a role in determining how the wave will interfere with itself.

2. When talking about orbitals what does phases actually mean (does it relate to charge
and electron spin)?

If you're talking about the phase of the wave function, it doesn't mean anything more than what it is. All particles are actually wave functions with some magnitude and phase at every point in space and time. That's just the way it is. You can see this phase angle because of the way wave functions interfere, such as in the http://en.wikipedia.org/wiki/Double-slit_experiment" .

3. What's the mechanic behind when phases cancel out to create
sigma*1s antibonding molecular orbital?

I would recommend studying the basics of quantum mechanics a little more before moving on to this stuff.
 
Last edited by a moderator:
  • #4
So I would assume the answer to no.3 is beyond AP Chem test range?

anyway thanks to the answers, they were very helpful

also is there any links for learning quantum physics, very interested in the subject.
 
Last edited:

Related to Wave function and orbital question

1. What is a wave function?

A wave function is a mathematical description of the probability of finding a particle in a certain location in space. It is a key concept in quantum mechanics and is used to describe the behavior of particles at the subatomic level.

2. What is the difference between a wave function and an orbital?

A wave function is a mathematical function that describes the probability of finding a particle in a certain location. An orbital, on the other hand, is a region of space around the nucleus where there is a high probability of finding an electron. In other words, an orbital is the physical representation of a wave function.

3. How is the wave function related to the quantum mechanical model of the atom?

The wave function is a key concept in the quantum mechanical model of the atom. It is used to describe the behavior of electrons in an atom, including their energy levels and locations in space. The quantum mechanical model is considered more accurate than the classical model, which only describes the behavior of particles as particles and not waves.

4. Can the wave function predict the exact location of a particle?

No, the wave function cannot predict the exact location of a particle. It only provides the probability of finding a particle in a certain location. This is due to the nature of quantum mechanics, where particles can behave as both particles and waves, making it impossible to know their exact location and momentum simultaneously.

5. How does the shape of an orbital relate to the wave function?

The shape of an orbital is directly related to the shape of the corresponding wave function. The wave function determines the probability of finding an electron in a certain location, and the shape of the orbital represents the region where there is a high probability of finding the electron. Different orbitals have different shapes, which correspond to different wave functions and energy levels.

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