Weak Acid/Strong Base Titration: Explaining pH at Equivalence

In summary, the equation pH = pKa + pHtitrant/2 can be used to estimate the pH at equivalence for a weak acid/strong base titration. However, it is only an approximation and may not always give the exact answer. It is based on the assumption that [H+] = √(Ka * Ca) and will only work for the titration of a weak base.
  • #1
nothing123
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For an weak acid/strong base titration, the pH at equivalence can be estimated by pH = pKa + pHtitrant/2. Can someone explain where that equation comes from?

Thanks.
 
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  • #2
nothing123 said:
For an weak acid/strong base titration, the pH at equivalence can be estimated by pH = pKa + pHtitrant/2.

Can you provide a source or link for that?

Because I don't think that's quite true; I tried your formula on an example weak acid/strong base problem in my analytical chemistry text and didn't get the right answer.
 
  • #3
I suppose what nothing refers to is

[tex][H^+] = \sqrt {K_a C_a}[/tex]

Just take the log. But it is only approximation and there are several assumptions done on the way to this equation. As shown it will work only for the titration of a weak base (Ka is for conjugated acid).
 

Related to Weak Acid/Strong Base Titration: Explaining pH at Equivalence

1. What is a weak acid/strong base titration?

A weak acid/strong base titration is a chemical process in which a strong base (such as sodium hydroxide) is added to a weak acid (such as acetic acid) in order to determine the concentration of the acid. The titration is typically performed by gradually adding the base to the acid until the solution reaches the point of equivalence, where the moles of acid and base are equal.

2. How is the pH at equivalence determined in a weak acid/strong base titration?

The pH at equivalence in a weak acid/strong base titration is determined by using an indicator or a pH meter. Indicators are substances that change color at a specific pH, allowing us to visually determine when the solution reaches the point of equivalence. A pH meter, on the other hand, measures the actual pH of the solution and can provide a more precise measurement.

3. What factors affect the pH at equivalence in a weak acid/strong base titration?

The pH at equivalence in a weak acid/strong base titration is affected by the strength of the acid and base involved, as well as the initial concentrations of the acid and base. Additionally, the volume of acid and base added and the choice of indicator can also impact the pH at equivalence.

4. How does the pH at equivalence relate to the strength of the acid and base?

The pH at equivalence in a weak acid/strong base titration can provide information about the relative strengths of the acid and base involved. If the pH at equivalence is closer to 7, it indicates that the acid and base are of similar strength. If the pH at equivalence is closer to the pH of the base (typically above 7), it indicates that the acid is weaker than the base. If the pH at equivalence is closer to the pH of the acid (typically below 7), it indicates that the acid is stronger than the base.

5. What is the significance of understanding the pH at equivalence in a weak acid/strong base titration?

Understanding the pH at equivalence in a weak acid/strong base titration can provide important information about the acid and base being used. It can help us determine the concentration of the acid, as well as the strength of the acid compared to the base. This knowledge can be useful in various scientific and industrial applications, such as in the production of medicines, food products, and other consumer goods.

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