What Determines the Maximum Number of Microstates at Equilibrium?

In summary, the product term ##\Omega(E_1)\Omega(E_2)## represents the total number of states for two non-interacting systems with energies ##E_1## and ##E_2##. This is because the first system can be in any of ##\Omega(E_1)## states and for each of these, the second system can be in any of ##\Omega(E_2)## states, resulting in a total of ##\Omega(E_1)\Omega(E_2)## possible states. This is similar to a system of two dice, where the first can be in six states and the second can be in six states, resulting in a total of thirty-six possible states for the two
  • #1
I_laff
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## \Omega(E_1)## is the number of microstates accessible to a system when it has an energy ##E_1## and ##\Omega(E_2)## is the number of microstates accessible to the system when it has an energy ##E_2##. I understand that each microstate has equal probability of being occupied, but could someone explain at equilibrium why ##\Omega(E_1)\Omega(E_2)## is the maximum number of microstates?
 
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  • #2
Such a product term means the total number of states

##\Omega(E_1,E_2)=\Omega(E_1)\Omega(E_2)##

of two non-interacting systems with energies ##E_1## and ##E_2##, respectively.
 
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  • #3
Lord Jestocost said:
Such a product term means the total number of states

##\Omega(E_1,E_2)=\Omega(E_1)\Omega(E_2)##

of two non-interacting systems with energies ##E_1## and ##E_2##, respectively.
Apologies if the answer is obvious, but why does ## \Omega(E_1)\Omega(E_2) ## give the total number of states?
 
  • #4
The first system may be in any of ##\Omega(E_1)## states; for any of these the second may be in any of ##\Omega(E_2)## states. It’s really no different than a system of consisting of two standard six-sided dice: the first may be in any of six states, the second may be in any of six states, so there are six times six equals thirty-six possible states for the two-dice system.
 
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  • #5
Nugatory said:
The first system may be in any of ##\Omega(E_1)## states; for any of these the second may be in any of ##\Omega(E_2)## states. It’s really no different than a system of consisting of two standard six-sided dice: the first may be in any of six states, the second may be in any of six states, so there are six times six equals thirty-six possible states for the two-dice system.
Ah of course. Thanks, that cleared things up.
 

What is a "most probable macrostate"?

A most probable macrostate refers to the state of a system that is most likely to occur based on the laws of thermodynamics and statistical mechanics. It is the state with the highest probability of being observed in a given system.

How is the most probable macrostate determined?

The most probable macrostate is determined by calculating the equilibrium state of a system using statistical mechanics. This involves taking into account the number of microstates (possible arrangements of particles) that correspond to a particular macrostate and using probability calculations to determine the most likely state.

What factors affect the probability of a most probable macrostate?

The probability of a most probable macrostate is affected by several factors, including the number of particles in the system, the temperature, and the energy of the system. These factors determine the number of microstates that correspond to a particular macrostate and therefore influence the likelihood of that state occurring.

Can a system be in more than one most probable macrostate?

No, a system can only be in one most probable macrostate at a given time. This state represents the most likely configuration of the system based on its energy and the laws of thermodynamics. However, a system can transition between different most probable macrostates as conditions change.

How does the concept of most probable macrostate relate to entropy?

The concept of most probable macrostate is closely related to entropy, which is a measure of the disorder or randomness in a system. The most probable macrostate is the state with the highest entropy, as it represents the most disordered arrangement of particles. As a system approaches equilibrium, it tends towards the most probable macrostate with the highest entropy.

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