What is the coffee ring of toluene and hexane?

In summary, when a coffee droplet is dropped and allowed to evaporate, a coffee ring is left behind due to the coffee not being able to evaporate. This is not the case with DI water droplets as nothing is dissolved in them. However, when Toluene or Hexane droplets are dropped and evaporate on a glass substrate, a ring is left behind indicating that something is dissolved in them. This could be due to impurities in the Toluene and Hexane or the cleanliness of the glass and the room it is in.
  • #1
Yinxiao Li
46
0
When we drop a coffee droplet and wait for it to evaporate, there is a coffee ring left. Because there is coffee dissolved in the solution, and when water can evaporate into the air, the coffee cannot evaporate and it will stay.

Therefore, if we drop one DI water droplet onto the substrate, there will be no such ring left because nothing is dissolved in the DI water.

Here comes the question: when I droplet one droplet of Toluene or Hexane onto a glass substrate, there is a ring after it evaporates! Toluene and Hexane are newly bought, and they should be good and pure. Then what does this ring come from? It means something is dissolved in the Hexane and Toluene. Any clues?
 
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  • #2
Do you know the purity of your toluene or hexane?
 
  • #3
Similarly, how clean is the glass? How clean is the room the glass/droplet are sitting in?
 
  • #4
256bits said:
Do you know the purity of your toluene or hexane?
you are right. Toluene is 95% pure.
 

1. What is the coffee ring effect?

The coffee ring effect is a phenomenon observed when a liquid, such as coffee or ink, dries on a surface. As the liquid evaporates, particles in the liquid are pulled towards the edges of the droplet, creating a ring-shaped stain.

2. What is toluene and hexane?

Toluene and hexane are both organic solvents commonly used in industry. Toluene is a clear, colorless liquid with a strong odor, while hexane is a colorless liquid with a mild odor. Both solvents are volatile, meaning they easily evaporate at room temperature.

3. What causes the coffee ring effect in toluene and hexane?

The coffee ring effect in toluene and hexane is caused by the difference in evaporation rates between the solvent and the particles suspended in it. As the solvent evaporates, the particles are pulled towards the edge of the droplet, resulting in the characteristic ring shape.

4. How does the coffee ring effect impact scientific research?

The coffee ring effect can have a significant impact on scientific research, especially in the field of nanotechnology. It can affect the uniformity and distribution of particles in a solution, which can impact the accuracy and reproducibility of experimental results.

5. Can the coffee ring effect be controlled or prevented?

Yes, the coffee ring effect can be controlled or prevented by adjusting the composition of the solvent or by using additives to modify the evaporation rate. Additionally, techniques such as spin coating or inkjet printing can be used to create more uniform and controlled patterns on a surface.

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