Why is Sn a better conductor than Pb?

In summary, the conversation is about the effect of Sn percentage on the electrical resistivity of SnPb solder in an extended essay on Physics. The person has found that Sn is a better conductor than Pb, despite periodic trends, and is seeking an explanation. There has been speculation about the role of electron-phonon coupling and lattice vibrations in this process, but no concrete answer has been found. They are also considering the size of the atoms and have provided some articles for further research. The conversation also mentions a simplified and a more complex explanation for electrical conductivity in metals.
  • #1
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Homework Statement


Hi guys, I'm currently writing an extended essay in Physics looking at the effect of percentage composition of Sn has on the electrical resistivity of SnPb Solder. I've noticed that Sn is listed as being a better conductor than Pb, despite trends of periodicity and have been trying to find an explanation for it.

2. The attempt at a solution
I've haven't really found much for a concrete answer, but I've been able to piece together that it has something to do with electron-phonon coupling, and that the amount of vibrations in the lattice allow Sn to conduct better but am still largely unsure as to how this process works.

If any of you super knowledgeable ones would be able to help me out, I'd be really grateful! :)
 
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  • #2

1. Why is Sn a better conductor than Pb?

The atomic structure of Sn and Pb is different. Sn has a more open and less packed structure compared to Pb, allowing for more movement of electrons and better conduction of electricity.

2. What is the role of valence electrons in the conductivity of Sn and Pb?

Both Sn and Pb have four valence electrons, but in Sn, they are located in the outermost shell and are more loosely bound compared to the inner shell of Pb. This allows for easier movement of electrons in Sn, making it a better conductor.

3. How does the size of Sn and Pb atoms affect their conductivity?

Sn atoms are smaller than Pb atoms, which means they have a higher density of electrons. This results in more frequent collisions between electrons, leading to better conductivity.

4. Is there a difference in the chemical properties of Sn and Pb that affects their conductivity?

While Sn and Pb have similar chemical properties, Sn is more reactive than Pb. This means that Sn can easily form bonds with other elements, making it a better conductor as it can transfer electrons more easily.

5. Are there any other factors besides atomic structure that contribute to Sn's superiority in conductivity?

Yes, temperature also plays a role. Sn has a lower melting point and is more malleable compared to Pb. This allows for better contact between metal particles, resulting in better conductivity.

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