Recent content by rabbed

  1. R

    A Equation system involving InverseDigamma(Digamma(a+1)-b*k)-1

    Thanks, i'll try that. If anyone has ideas for an analytic solution, just shoot :)
  2. R

    A Equation system involving InverseDigamma(Digamma(a+1)-b*k)-1

    How would one go about solving this for a and b given N, E and K? n(0) + n(1) + … + n(K) = N n(0)*0 + n(1)*1 + … + n(K)*K = E Where n(k) = InverseDigamma(Digamma(a+1)-b*k)-1
  3. R

    I Boltzmann Distribution: Formula & Fig 2a in Document

    Doh! So simple, thanks!
  4. R

    I Boltzmann Distribution: Formula & Fig 2a in Document

    funny, But what values to put in? Around x=1 it seems to get y=200 e^(ln(600)-1/(1.381×10^-23*300)) = 0?
  5. R

    I Boltzmann Distribution: Formula & Fig 2a in Document

    Hello Can anyone explain what formula (or parameters) was used to create the exponential Boltzmann distribution in fig 2a of this document? http://image.sciencenet.cn/olddata/kexue.com.cn/upload/blog/file/2009/5/20095251352697121.pdf I figure it must be something like y=e^(ln(600)-b*x) for some b?
  6. R

    I Can the Exact Boltzmann Distribution Yield Specific Quantum State Populations?

    Thank you for answering! Seen as a strictly mathematical problem (N distinct balls in K distinct boxes labeled with increasing integer scores) there is an actual right answer/distribution with a probability, so why wouldn’t we want that instead of relying on some random answer that depend on how...
  7. R

    I Can the Exact Boltzmann Distribution Yield Specific Quantum State Populations?

    I think the issue is that there should really be another constraint - that the ni’s should be integers. Otherwise the answers won’t make much physical sense (non-integer occupancy numbers). We’re relying on the Digamma function coming from a Gamma function which can be defined in multiple ways...
  8. R

    I Can the Exact Boltzmann Distribution Yield Specific Quantum State Populations?

    Hi With the exact Boltzmann distribution, ni = InverseDigamma(-α-β*εi)-1: https://studyres.com/doc/269738/revision-of-boltzmann-statistics-for-a-finite-number-of-p... Shouldn't I be able to get (n0, n1, n2, n3, n4, n5, n6, n7) = (6, 3, 2, 0, 0, 0, 0, 0) for some α and β, if N=11, E=7 and Δε=1...
  9. R

    I Using the ni Formula from a Paper with N=7: What do I Get?

    Yes, I can't find the actual paper either but that abstract (as well as another abstract from him) makes the derivation clear: digamma(ni+1) = a-b*ei use approximation digamma(x+1) = ln(e^-m+x) where m = 0.5772156649 ln(e^-m+ni) = a-b*ei e^-m+ni = e^(a-b*ei) ni = e^(a-b*ei)-e^-m ni =...
  10. R

    I Using the ni Formula from a Paper with N=7: What do I Get?

    Hi How do I use this formula: ni = (e^(B*(eH-ei))-1)*e^(-0.5772156649..) from this paper? https://ui.adsabs.harvard.edu/abs/2018DDA...49P...2C/abstract According to this site, (n0,n1,n2,n3,n4,n5,n6,n7) = (3,2,1,1,0,0,0,0) for N=7: https://bouman.chem.georgetown.edu/S02/lect21/lect21.htm Does...
  11. R

    A What is the derivation of the exact Maxwell-Boltzmann distribution?

    I believe the most probable macrostate (for 6 particles, constant energy 6) is achieved with occupancy 3,1,1,1,0,0,0 in energy levels 0,1,2,3,4,5,6. Is the solution to take the outputs from the following calculation (where I've picked suitable values a=-0.06 and b=1.96 to fit the solution, but...
  12. R

    A What is the derivation of the exact Maxwell-Boltzmann distribution?

    I would like to see a derivation of the exact Maxwell-Boltzmann distribution shown as (16) in this document: https://www.researchgate.net/publication/222670999_Exact_Maxwell-Boltzmann_Bose-Einstein_and_Fermi-Dirac_Statistics This is my starting point (f being the function to maximize, g and h...
  13. R

    I Configuration probability of partitioned objects

    With N objects, if I arrange each without replacement into K distinct partitions in which different object orders should not be accounted for: - For distinct objects I get a total number of Wtot = K^N ways to partition them, and a specific distribution with N1 objects in partition 1, N2 objects...
  14. R

    I Boltzmann particle distinguishability

    Nevermind.. It helped seeing indexing (treat identical as distinct) and faculty division (of the number of objects considered identical) as a means of adding and removing order into account of the number of ways. We can distribute N distinct balls into one box in 1 way (if we don’t care about...
  15. R

    I Boltzmann particle distinguishability

    Still having some issues with this. Could you say something more about the reasoning why (1 | 2A 2B) and (1 | 2B 2A) should count as just one "number of ways" instead of two? Is there any way to practically get the number of ways? Would it help to make some trials manually and create a PMF?
Back
Top