Spectrophotometric Reference for Inorganics?

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Discussion Overview

The discussion centers around the availability of absorbance spectra and extinction coefficients for common inorganic substances, particularly salts like potassium and sodium salts. Participants explore the capabilities of spectrophotometers in measuring these substances and seek specific data to apply Beer's Law for concentration calculations.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant expresses a need for absorbance spectra and extinction coefficients for inorganic salts, indicating difficulty in finding such information primarily available for biological substances.
  • Another participant questions the visibility of NaCl solutions and suggests considering different regions of the spectrum (visible, infrared, UV) for measurement.
  • A participant mentions uncertainty about the applicability of spectrophotometry to sodium chloride and requests a comprehensive absorbance spectrum for various salts, suggesting that such data should be available in chemical handbooks.
  • One participant provides a resource link to the NIST Chemistry WebBook and suggests looking for original research articles, noting that older studies may be more accessible for free.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the availability of data for inorganic salts or the suitability of specific salts for spectrophotometric analysis. Multiple viewpoints regarding the visibility and measurement of these substances remain present.

Contextual Notes

Participants express limitations in finding specific absorbance data and the potential challenges related to the visibility of certain salt solutions in spectrophotometric measurements.

mishima
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I am looking for absorbance spectra and extinction coefficients (molar absorptivities) for common inorganic substances like potassium and sodium salts. I am only finding this information for biological substances.

Am I misinterpreting what the spectrophotometer can do? I would like to, for example, use Beer's Law to calculate concentration of a salt in solution after measuring absorbance with a known extinction coefficient.
 
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Visible?

Does the NaCl solution look colored?

Infrared? UV?
 
I mean salts in general, like potassium permanganate or copper (II) nitrate. I am unaware if sodium chloride can be used with a spectrophotometer; I was under the impression that some could not.

would like an absorbance spectrum (absorbance vs. wavelength), so all wavelengths. I would have thought this information would be tabulated somewhere, like a chemical handbook, but I am not finding it.
 
You can try here: http://webbook.nist.gov/chemistry/

Failing that you should just try to find the original research. It will likely be old which makes it (kind of) easier to find them for free.
 

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