How Does the London van der Waals Force Relate to the Casimir Effect?

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SUMMARY

The London van der Waals force is mathematically expressed as F = -c * a^-7, where 'a' represents the distance between two neutral atoms and 'c' is defined by C = -23 * ħ * c / (4π * (α1 * α2)). Here, α1 and α2 are calculated as (ε - 1) / (4π * N), with N being the atom number density and ε the permittivity. The Casimir force, which is derived from the interactions between neutral atoms, is distinct from the van der Waals force and is influenced by the geometry of the system. Notably, the Casimir force can be repulsive between two metal hemispheres, a concept explored by E. M. Lif****z and J. Schwinger in the 1950s.

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  • Understanding of quantum mechanics principles
  • Familiarity with the concepts of van der Waals forces
  • Knowledge of the Casimir effect and its implications
  • Basic grasp of atomic structure and density calculations
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  • Research the mathematical derivation of the Casimir effect
  • Explore E. M. Lif****z's original paper on the Casimir effect
  • Study the relationship between van der Waals forces and molecular interactions
  • Investigate experimental setups demonstrating the Casimir force
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Physicists, researchers in quantum mechanics, and anyone studying atomic interactions and forces in condensed matter physics will benefit from this discussion.

Kruger
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The London van der Waals force is approximatly given by F=-c *a^-7 where a is the distance between two neutral atoms and c is something like this:

C=-23*hbar*c/4pi*(alpha1*alpha2)

where alpha1 and alpha2 =(epsilon-1)/(4pi*N)

and N is the atom number density and epsilon the permittivity.

--> Question 1: Does that mean if I have a body with 10^30 atoms the moledule number density is 10^30?

Now from the force between neutral atoms we can get to the Casimir-force. We can then just calclulate how much one atom of Plate A is attracted by the atoms of the other plates. Doing so with all atoms on Plate A we can sum over all the resulting forces and have the Casimir-Force.

Question 2: is this correct?
 
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Kruger said:
The London van der Waals force is approximatly given by F=-c *a^-7 where a is the distance between two neutral atoms and c is something like this:
C=-23*hbar*c/4pi*(alpha1*alpha2)
where alpha1 and alpha2 =(epsilon-1)/(4pi*N)
and N is the atom number density and epsilon the permittivity.
--> Question 1: Does that mean if I have a body with 10^30 atoms the moledule number density is 10^30?
Now from the force between neutral atoms we can get to the Casimir-force.
The molecule number density cannot be dimensionless, so you have to divide 10^30 by the volume of the body.
 
The Casimir force is related but not identical to the van der Waals force, a fact which was first explicitly demonstrated by E. M. Lif****z and later J. Schwinger in the 1950's. In particular, the Casimir force is strongly dependent on the geometry of the system and is actually repulsive between two metal hemispheres. This revelation spoiled Schwinger's attempt to explain sonoluminescence using the Casimir force.


Lif****z's Paper:
E. M. Lif****z, Sov. Phys. JETP 2, 73, 1956

A nice experiment and good discussion:
http://prola.aps.org/abstract/PRL/v78/i1/p5_1

Edit: Ha! This is somewhat absurd, I can't write Lif****z's name because it has **** in it.
 
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