Absolute temperature for average translational kinetic energ

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SUMMARY

The discussion centers on calculating the change in electric potential energy for an ammonia molecule (NH3) in an electric field of 1.3×106 N/C and determining the absolute temperature at which the average translational kinetic energy equals this potential energy change. The potential energy change was calculated as 6.5E-24 J. The user attempted to derive the temperature using the relationship between kinetic energy and potential energy but mistakenly used the wrong value for the Boltzmann constant, confusing it with the electrostatic constant (8.99E9 Nm2/C2).

PREREQUISITES
  • Understanding of electric potential energy (U = -p . E)
  • Familiarity with the Boltzmann constant (k ≈ 1.38×10-23 J/K)
  • Knowledge of translational kinetic energy (KE = 3/2 kT)
  • Basic principles of molecular dipole moments
NEXT STEPS
  • Review the concept of electric dipole moments and their behavior in electric fields
  • Study the relationship between kinetic energy and potential energy in thermodynamics
  • Learn about the Boltzmann constant and its applications in statistical mechanics
  • Explore the implications of thermal agitation on molecular alignment in electric fields
USEFUL FOR

Students studying thermodynamics, physics enthusiasts, and anyone interested in molecular behavior in electric fields.

rsatchel
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Homework Statement


The ammonia molecule (NH3) has a dipole moment of 5.0×10−30C⋅m. Ammonia molecules in the gas phase are placed in a uniform electric field E⃗ with magnitude 1.3×106 N/C .

Part A:
What is the change in electric potential energy when the dipole moment of a molecule changes its orientation with respect to E⃗ from parallel to perpendicular?

Part B:
At what absolute temperature T is the average translational kinetic energy 3/2 kT of a molecule equal to the change in potential energy calculated in part (a)? (Note: Above this temperature, thermal agitation prevents the dipoles from aligning with the electric field.)

Homework Equations


U = -p . E
T = p X E

The Attempt at a Solution


[/B]
I got Part A:
delta U = p. E = p E cos theta = (5.0E-30)(1.3E6) = -6.5E-24 J,

so delta U = 6.5E-24J

Part B:

My reasoning is as follows:
KE + PE = 0
3/2 kT + U = 0
U = -3/2 kT
(-2/3 U) / k = T
T = (-2/3)(6.5E-24) / (8.99E9) = 482E-36 degrees K

which is wrong.
I don't know what I'm doing wrong :/
 
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What is k and what is its value?
 
DrClaude said:
What is k and what is its value?

I thought it was maybe: k = 8.99E9 Nm^2/C^2
 
Use Boltzmann constant for k, it is approximately 1.38*10^-23 J/K
 

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