Absolute temperature for average translational kinetic energ

Click For Summary

Homework Help Overview

The discussion revolves around the change in electric potential energy of ammonia molecules in an electric field and its relation to absolute temperature and average translational kinetic energy. The problem involves concepts from thermodynamics and electrostatics.

Discussion Character

  • Mixed

Approaches and Questions Raised

  • The original poster attempts to calculate the change in potential energy when the dipole moment of ammonia changes orientation and relates this to the average translational kinetic energy at a specific temperature. Some participants question the value of the constant used in the calculations.

Discussion Status

Participants are exploring the calculations related to potential energy and temperature. There is a focus on clarifying the value of the constant 'k' used in the equations, with some guidance provided regarding the correct constant to use.

Contextual Notes

There is a noted misunderstanding regarding the value of the constant 'k', with participants discussing its significance in the context of the problem.

rsatchel
Messages
6
Reaction score
0

Homework Statement


The ammonia molecule (NH3) has a dipole moment of 5.0×10−30C⋅m. Ammonia molecules in the gas phase are placed in a uniform electric field E⃗ with magnitude 1.3×106 N/C .

Part A:
What is the change in electric potential energy when the dipole moment of a molecule changes its orientation with respect to E⃗ from parallel to perpendicular?

Part B:
At what absolute temperature T is the average translational kinetic energy 3/2 kT of a molecule equal to the change in potential energy calculated in part (a)? (Note: Above this temperature, thermal agitation prevents the dipoles from aligning with the electric field.)

Homework Equations


U = -p . E
T = p X E

The Attempt at a Solution


[/B]
I got Part A:
delta U = p. E = p E cos theta = (5.0E-30)(1.3E6) = -6.5E-24 J,

so delta U = 6.5E-24J

Part B:

My reasoning is as follows:
KE + PE = 0
3/2 kT + U = 0
U = -3/2 kT
(-2/3 U) / k = T
T = (-2/3)(6.5E-24) / (8.99E9) = 482E-36 degrees K

which is wrong.
I don't know what I'm doing wrong :/
 
Physics news on Phys.org
What is k and what is its value?
 
DrClaude said:
What is k and what is its value?

I thought it was maybe: k = 8.99E9 Nm^2/C^2
 
Use Boltzmann constant for k, it is approximately 1.38*10^-23 J/K
 

Similar threads

  • · Replies 1 ·
Replies
1
Views
2K
Replies
1
Views
2K
  • · Replies 4 ·
Replies
4
Views
2K
  • · Replies 2 ·
Replies
2
Views
7K
  • · Replies 39 ·
2
Replies
39
Views
5K
  • · Replies 1 ·
Replies
1
Views
2K
Replies
2
Views
4K
Replies
14
Views
4K
Replies
17
Views
4K
  • · Replies 21 ·
Replies
21
Views
3K