Absorption and emission spectrum in quantum optics

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SUMMARY

The discussion focuses on the emission and absorption spectra in quantum optics, specifically referencing key textbooks such as "Quantum Optics" by Scully and Zubairy, Walls and Milburn, and Chiao and Garrison. The formula for resonance fluorescence is provided, relating the electric field operator to atomic operators. The conversation also highlights the significance of the dipole moment auto-correlation function in determining both absorption coefficients and emissivities, as discussed in the review paper by van Vleck and Huber. Additionally, the Green-Kubo formula is mentioned as a fundamental principle in linear-response theory.

PREREQUISITES
  • Understanding of quantum optics principles
  • Familiarity with resonance fluorescence and its mathematical representation
  • Knowledge of dipole moment auto-correlation functions
  • Basic concepts of linear-response theory and the Green-Kubo formula
NEXT STEPS
  • Study the absorption spectrum in quantum mechanics
  • Explore the implications of local vibrational modes on emission and absorption spectra
  • Review the Green-Kubo formula in detail
  • Investigate the spectral line shapes as described by van Vleck and Huber
USEFUL FOR

Researchers and students in quantum optics, physicists studying atomic interactions, and anyone interested in the mathematical foundations of emission and absorption spectra.

Cedric Chia
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TL;DR
Absorption spectrum for a quantum dot
The emission spectrum or resonance fluorescence for a quantum dot, atom or defect center are discussed in many quantum optics textbook, for example see "Quantum Optics" by Marlan O. Scully and M. Suhail Zubairy Chapter 10 , "Quantum Optics" by D. F. Walls and Gerard J. Milburn Chapter 10 and "Quantum Optics" by Raymond Chiao and John Garrison Chapter 14.

In these textbooks, the formula for resonance fluorescence is given by:
$$
\alpha(\omega)=Re\int_0^{\infty}dt\left<E^{(-)}(t)E^{(+)}(t+\tau)\right>e^{i\omega\tau}
$$
where one usually relates the electric field operator with the atomic raising/lowering operator:
$$
\left<E^{(+)}(t)\right>\propto\left<\sigma\right>
$$

But what about the formula for absorption spectrum? Where can I find discussion on the absorption spectrum? And what if I have a system coupled to local vibrational modes (a polaron), how would that change the formula of emission and absorption spectrum?
 
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I know very little about quantum dots, but I do remember a review paper on spectral line shapes: van Vleck J H and Huber D L 1977, Rev. Mod. Phys. 49, 939-959. Both, absorption coefficients and emissivities can be expressed in terms of Fourier transforms of the dipole moment auto-correlation function, or more generally, of the current density fluctuations.
 
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WernerQH said:
spectral line shapes: van Vleck J H and Huber D L 1977, Rev. Mod. Phys. 49, 939-959. Both, absorption coefficients and emissivities can be expressed in terms of Fourier transforms of the dipole moment auto-correlation function, or more generally, of the current density fluctuations.
Is this not found in spectroscopy texts/monographs (or at least rather quantum mechanical ones as opposed to semiclassical)?
 
That's a very general basic principle. In linear-response theory the response function is given in terms of the (retarded) autocorrelation function of the source. It's also known as the Green-Kubo formula.
 
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