Activation energy and pre exponential factor

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SUMMARY

The discussion focuses on calculating the activation energy (Ea) and the pre-exponential factor (A) for a chemical reaction using temperature and rate constant data. The calculated activation energy is 64 kJ/mol, derived from the equation Ea = - (R * gradient), where R is the gas constant. The pre-exponential factor is intended to be calculated using the formula A = E^(LN k + Ea/RT), but the user encounters issues inputting the values into their calculator. The specific values used include a gradient of 0.7703 and a temperature of 293 K.

PREREQUISITES
  • Understanding of Arrhenius equation and its components
  • Familiarity with Excel for data plotting
  • Knowledge of gas constant (R = 8.314 J/(mol·K))
  • Basic calculator operations involving exponentials and logarithms
NEXT STEPS
  • Review the Arrhenius equation and its application in chemical kinetics
  • Learn how to accurately input exponential and logarithmic functions on scientific calculators
  • Explore the significance of activation energy in reaction mechanisms
  • Investigate common errors in calculating pre-exponential factors
USEFUL FOR

Chemistry students, educators, and professionals involved in chemical kinetics and reaction rate analysis will benefit from this discussion.

Diamond101
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Homework Statement


Calculate activation energy and pre exponential factor, i need help with the pre exponential factor

Homework Equations


Temperature °C
-20 = 253 k
-10= 263
0=273
10=283
20=293
Rate const. s-1
1.15
3.85
11.3
28.7
74.0

The Attempt at a Solution


i already plotted the graph on excel . i got ea= -(r * gradient)= -8.314*0.7703*10^4) =64 kj/mol
Pre exponential factor= E^(LN k + ea/RT) ^=E^(4.3+ 64/ 8.314*293 K) =?
 
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What's the problem with keying these numbers into the calculator?
 

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