Alka-Seltzer + Soap reaction rate

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SUMMARY

The addition of dish soap to water before dissolving Alka-Seltzer significantly slows the reaction rate. This occurs because the surfactant in the soap coats the Alka-Seltzer tablet, hindering the interaction between the solid components and water. Alka-Seltzer consists of bicarbonate and citric acid, both of which must dissolve for the reaction to proceed. The detergent likely forms a weak coating over the citric acid, further impeding the reaction.

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chemkid1234
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Hello,

I have seen that adding dish soap to water and then dissolving Alka-Seltzer in the solution causes the reaction rate to slow. Does anybody have any idea as to why this happens?
 
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The surfactant must coat the tablet and this coating slows the reaction between the solid surface and the water. The tablet is a mix of bicarbonate and citric acid. These both must dissolve into the water before a reaction can occur. Perhaps the detergent has an affinity to one of reactants, likely citric acid, and forms a weak coating over it.
 

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