Aluminum Ion Detection with AAS: Can 0.00014% Al 3+ be Detected?

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Discussion Overview

The discussion revolves around the detection of aluminum ions (Al 3+) in a solution with a concentration of 0.00014% using Atomic Absorption Spectroscopy (AAS). Participants explore the relationship between concentration expressed as a percentage and the detection limit of 2 mg/L for aluminum ions.

Discussion Character

  • Homework-related, Mathematical reasoning

Main Points Raised

  • One participant calculates that 0.00014% of Al 3+ corresponds to 0.0037772g of Al 3+ and seeks to compare this to the detection limit.
  • Another participant suggests that concentration in percentage typically refers to weight/volume (w/v) or weight/weight (w/w), prompting a conversion to compare with the detection limit.
  • Clarification is provided regarding the definitions of w/v and w/w by a participant.
  • Further calculations are proposed, with one participant determining that 0.00014% equates to 0.0014g/L or 1.4 mg/L.
  • A later reply concludes that the concentration is detectable based on the calculations discussed.

Areas of Agreement / Disagreement

Participants generally agree on the method of converting the percentage concentration to a comparable unit for detection limits, though the discussion includes varying interpretations of the initial percentage and its implications for detection.

Contextual Notes

Some assumptions about the definitions of concentration types (w/v vs. w/w) and the conversion process may not be universally understood, leading to potential confusion in calculations.

14h54
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Hi, I need help with a question on my lab worksheet.

Homework Statement


A solution is 0.00014% in Al 3+ ion. The detection limit for aluminum ion is 2 mg/L using AAS. Would the aluminum ion in this solution be detected by AAS?


Homework Equations


1 mg/L = 1 mg/1000mL which corresponds to 1 mg/1000g


The Attempt at a Solution



I feel like 0.00014% of Al 3+ means 0.0037772g of Al 3+ (0.00014*26.98g/mol). I then have to compare that to going from 2 mg/L to some percentage? We didn't do any calculations in lab other than finding the volume for Pb 2+ & HNO3 needed for our specified ppm.

I honestly have no clue how to go about this.


Thank you for the help.
 
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Usually, when a concentration is described in a percentage it means w/v or w/w, not molarity. So all you have to do is figure out w/v or w/w (which are practically equal here), and see how it compares to 2 mg/l.
 
What do you mean by w/v or w/w?
 
Weight per volume or weight per weight.
 
So 0.00014% would mean 1.4E-7g per .1 L?
And I would then have to covert 2 mg/L to g/L and compare?
 
It equates to 0.00014g/0.1l, so 0.0014g/l or 1.4 mg/l, if I'm not mistaken.
 
I see now.

And thus the answer would be yes.

Thank you for your help.
 
Last edited:

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