Average Distance Between Neighboring N2 Molecules at NTP

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Discussion Overview

The discussion revolves around calculating the average distance between neighboring nitrogen (N2) molecules at normal temperature and pressure (NTP), assuming the molecules are spherical. Participants explore geometric approaches and the implications of volume distribution among gas molecules.

Discussion Character

  • Homework-related
  • Mathematical reasoning
  • Debate/contested

Main Points Raised

  • One participant presents a formula for the average distance based on the volume available to an N2 molecule, calculated from the ideal gas volume at NTP divided by Avogadro's number.
  • Another participant suggests using simple geometry, proposing that if molecules are evenly spread, each occupies a cube, and the distance between them can be derived from the cube's dimensions.
  • A later reply questions how to find the distance between molecules if they are adjacent cubes, seeking clarification on the geometric approach.
  • One participant asserts that the length of the cube can be calculated as the cube root of the volume, which is confirmed by another participant.
  • However, a participant points out a discrepancy between their calculated distance (3.33*10^-7 cm) and a provided answer (2.07*10^-7 cm), indicating confusion over the correct interpretation of volume and distance.
  • Another participant critiques the assumption that the distance between molecules can be represented as the radius of a sphere, arguing that this does not account for the overlapping volumes of adjacent molecules and that spheres only occupy about 74% of the available volume.
  • This participant also emphasizes that the shape of the molecules is irrelevant to the distance calculation since the distance is significantly larger than the size of the molecules themselves.

Areas of Agreement / Disagreement

Participants express differing views on the correct method to calculate the average distance between N2 molecules, with no consensus reached on the appropriate formula or interpretation of the volume occupied by the molecules.

Contextual Notes

There are unresolved assumptions regarding the geometric representation of gas molecules and the implications of their shapes on volume calculations. The discussion highlights the complexity of modeling molecular distances in gases.

Mandavi
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Homework Statement


What is the average distance between neighboring molecules if N2 molecule is assumed to be spherical?(Average volume available to a molecule of N2 gas at NTP
is 3.72*10^-20 cm^3,which has been calculated by dividing 22.4 litres by Avogadro's number)


Homework Equations


Volume occupied by an ideal gas at NTP is 22.4 litres.
Avogadro's number is 6.022*10^23.


The Attempt at a Solution


Going by the information in the brackets,we have considered that each and every part of the volume is occupied by an N2 molecule,then how are we supposed to find out the average distance between them?Is there a formula for it?If so,please do explain it along with its conditions.
Thank you.
 
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Simple geometry. Imagine that molecules are evenly spread, and each one is inside its own cube...

--
 
Let the gas molecule be at the center of the cube. What is the distance between the centers of the cubes?
 
the length of the cube.
 
the length of the cube which can be obtained by calculating the cube root of the volume.right?
 
But,the answer coming this way is different from the answer given!
As per the cube root of volume,answer is coming as 3.33*10^-7 cm,but the answer given is 2.07*10^-7 cm.
 
Answer given is radius of the sphere of a given volume, but it is very wrong. First - if the distance between molecules equals R, volume available to the molecule is not that of a sphere with radius R, as part of this sphere belongs to the other molecule. Second - spheres don't occupy whole available volume, but only about 74% (see http://en.wikipedia.org/wiki/Kepler_conjecture).

Also note, that shape of the molecules is in this case completely meaningless, as the distance between molecules is much larger than the molecule itself, so shape is in no way connected with the volume available to the molecule.

--
methods
 
  • #10
Borek said:
Answer given is radius of the sphere of a given volume, but it is very wrong. First - if the distance between molecules equals R, volume available to the molecule is not that of a sphere with radius R, as part of this sphere belongs to the other molecule. Second - spheres don't occupy whole available volume, but only about 74% (see http://en.wikipedia.org/wiki/Kepler_conjecture).

Also note, that shape of the molecules is in this case completely meaningless, as the distance between molecules is much larger than the molecule itself, so shape is in no way connected with the volume available to the molecule.

--
chemical calculators - buffer calculator, concentration calculator
www.titrations.info - all about titration methods

Exactly!Thanks a zillion!:smile:
 

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