Balmer series for atomic hydrogen lie

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SUMMARY

The discussion focuses on calculating the Rydberg constant (RH) for atomic hydrogen using the Balmer series wavelengths: λ = 656.46 nm, 486.27 nm, 434.17 nm, and 410.29 nm. The calculated value for RH is 1.097 x 107 m-1. To find the ionization energy (I), the longest wavelength from the Balmer series should be used in the equation E = hc/λ, which relates energy to wavelength. The Balmer series starts at n=3 because it represents transitions from higher energy levels (n=3 and above) to n=2, resulting in the emission of visible light.

PREREQUISITES
  • Understanding of the Rydberg formula for hydrogen spectral lines
  • Familiarity with the concepts of wavelength and energy in quantum mechanics
  • Knowledge of Planck's constant (h) and the speed of light (c)
  • Basic principles of atomic structure and electron transitions
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  • Research the derivation of the Rydberg formula for hydrogen
  • Learn about the relationship between wavelength and energy in quantum mechanics
  • Study the concept of ionization energy and its significance in atomic physics
  • Explore the differences between emission and absorption spectra in atomic transitions
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Students studying quantum mechanics, physicists interested in atomic spectra, and educators teaching atomic structure and spectral analysis.

xregina12
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Homework Statement



The first few lines of the Balmer series for atomic hydrogen lie at the wavelengths λ = 656.46, 486.27, 434.17, 410.29nm, ... Find a value for RH, the Rydberg constant for hydrogen. The ionization energy I is the minimum energy required to remove the electron. Find it from the data. How is I related to RH? (Hint: the ionization limit corresponds to n → ∞ for the final state of the electron).

I used the equation: 1/lambda = R (1/4 - 1/n^2) where R is Rydberg constant and n=3, 4, 5 respectively and got that R=1.097 x 10 ^7. However, I am not sure what to do to find the minimum ionization energy. The only equation I thought I can use is E=hc/lambda=hcR(1/4-1/n^2). For Also I know that since it's the minimum energy required to remove the electron, I should use the longest wavelength given to figure out the ionization energy. Can someone please explain to me the second part of the problem to me? Also, why does n for the Balmer series start at 3? Please help me. Thank you!
 
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xregina12 said:

Homework Statement

However, I am not sure what to do to find the minimum ionization energy. The only equation I thought I can use is E=hc/lambda=hcR(1/4-1/n^2).
Look at the hint.
Also, why does n for the Balmer series start at 3? Please help me. Thank you!

Because Balmer lines is the name given to spectral line *emissions* of the hydrogen atom. For electron going from n=1 to n=2, a photon is absorbed, not emitted.
 

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