Bloch wavepackets and the Pauli exclusion principle

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Discussion Overview

The discussion revolves around the use of wavepackets in solid state physics, specifically in relation to the semiclassical approach and the implications of the Pauli exclusion principle. Participants explore how wavepackets can be constructed from Bloch states and the potential conflict this presents with the exclusion principle when multiple electrons occupy states close in momentum space.

Discussion Character

  • Exploratory
  • Debate/contested
  • Technical explanation

Main Points Raised

  • Peter questions how forming a wavepacket that spans multiple Bloch vectors k could lead to a violation of the Pauli exclusion principle, given that another electron could occupy a state k' adjacent to k.
  • In response, Peter later suggests that the Pauli exclusion principle is satisfied because the wave function must be antisymmetric with respect to particle exchange, even if wavepackets are centered around similar k values.
  • Peter acknowledges a potential oversight in his explanation regarding the time development in the wavefunction, emphasizing that symmetrization is valid for wavepackets not centered around the same eigenvalue k.

Areas of Agreement / Disagreement

Participants express differing views on the implications of wavepackets for the Pauli exclusion principle, with no clear consensus reached on the correctness of the interpretations presented.

Contextual Notes

There are unresolved aspects regarding the mathematical treatment of wavepackets and their time evolution, as well as the specific conditions under which the Pauli exclusion principle applies in this context.

pedda
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Hello,

I have a question concerning the use of wavepackets to justify the semiclassical approach in solid state physics. In Ashcroft/Mermin, the authors briefly mention that we can construct wave packets and then use them to describe the motion of the center which can be interpreted as what one usually calls the point particle electron. Now, the problem that I have is that for each state there is one Bloch vector k. If I was to form a wave packet spreading over several k, how can there be a second electron occupying the state k' that is right next to k? The packet centered around k will definitely have components of wave vector k' and vice versa. Doesn't this violate the pauli exclusion principle?

- Peter
 
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I have the same question :(. Did you manage to resolve it Peter??
 
Hey,

yes, I did resolve it for me, but I don't know if it is correct. The Pauli exclusion principle states that the wave function has to be antisymmetric with respect to the exchange of particles. The fact that you have two wavepackets centered around two different ks doesn't violate this principle, even if they are centered at the same place. You can write down the wavefunction for two gaussian wavepackets in the position representation. You will see that you will get something like

e^{-(x_1-ik_1)^2}e^{-(x_2-ik_2)^2}-e^{-(x_1-ik_2)^2}e^{-(x_2-ik_1)^2}

+ some prefactors and other stuff. As you see, no problem here!

Hope this helps, Peter
 
I don't see any way to edit my last post, but an important part that I left out is the actual time development that appears in the denominator of the exponentials, so don't take what I've written too seriously. The most important part is that symmetrization works even for wavepackets as long as they are not centered around the same eigenvalue k.
 

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