Bonding Symbols? Understanding Oxygen & Hydrogen Bonds

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    Bonding Symbols
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Discussion Overview

The discussion centers on understanding the bonding symbols in a diagram of hydrogen peroxide, specifically the representation of bonds between oxygen and hydrogen atoms. The scope includes conceptual clarification of chemical bonding and molecular geometry.

Discussion Character

  • Conceptual clarification, Debate/contested

Main Points Raised

  • One participant identifies the bond between the two oxygen atoms as a single sigma bond, questioning the meaning of the thicker triangular bond line and dotted lines representing the hydrogen-oxygen bonds.
  • Another participant suggests that the representation indicates that the bonds connecting hydrogen and oxygen are perpendicular to each other.
  • A different participant challenges the idea of perpendicular bonds, referring to external resources and stating that the relevant dihedral angle in hydrogen peroxide is not 90 degrees.
  • Another reply clarifies that the bonds are not perpendicular but rather that one bond is below the surface while the other is above, noting that these bonds are often tetrahedral but lack a rigid convention.

Areas of Agreement / Disagreement

Participants express differing views on the interpretation of the bond representations, with no consensus reached regarding the angles or the nature of the bond orientations.

Contextual Notes

There are limitations in the discussion regarding the assumptions about bond angles and the lack of a standard convention for representing molecular geometry in diagrams.

FeDeX_LaTeX
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Hello;

I don't understand the symbols drawn on this diagram;

http://upload.wikimedia.org/wikipedia/commons/8/8e/Wasserstoffperoxid.svg

I understand that the bond between the two oxygen atoms is a single sigma bond (illustrated by a -), but what are the bonds between the oxygen and hydrogen atoms on both sides (a thicker, triangular bond line and dotted lines)?

Thanks.
 
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hi,
it is just a representation to understand that the bond, which connects H and O, are perpendicular to each other!
 
Not perpendicular, just one is below the surface while another is above. Most often these are tetrahedral, but not necessarily, there is no rigid convention behind.
 

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