Breakdown of Planck's Law under certain Conditions

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SUMMARY

The discussion focuses on the distinctions between Planck's Law and Rayleigh-Jeans' Law, particularly in the context of blackbody radiation. It is established that while Planck's Law remains valid under various conditions, its assumptions may break down when the size of the blackbody cavity is small and the temperature is low, leading to significant deviations. The average energy per mode in Rayleigh-Jeans' Law is expressed as ##kT##, while in Planck's Law, it is given by ##\frac{hc}{λ(e^\frac{hc}{λkT}-1)}##. The breakdown of Planck's Law is attributed to the failure of the quasi-continuous energy spectrum assumption in these extreme conditions.

PREREQUISITES
  • Understanding of Planck's Law and Rayleigh-Jeans' Law
  • Familiarity with blackbody radiation concepts
  • Knowledge of energy quantization and spectrum analysis
  • Basic grasp of thermodynamics and temperature effects on radiation
NEXT STEPS
  • Research the implications of small cavity sizes on blackbody radiation
  • Study the derivation and assumptions of Planck's Law in detail
  • Explore experimental techniques for measuring spectra in tiny cavities
  • Investigate the behavior of materials at low temperatures and their energy spectra
USEFUL FOR

Physicists, particularly those specializing in thermodynamics, quantum mechanics, and experimental physics, will benefit from this discussion, especially those interested in the limitations of Planck's Law under specific conditions.

tade
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The difference between Planck's Law and the Rayleigh-Jeans' Law is, in Rayleigh Jeans, the average energy per mode is ##kT##, whereas in Planck, it is ##\frac{hc}{λ(e^\frac{hc}{λkT}-1)}##.

These average energy formulas are multiplied by another formula to give either Planck's Law or the Rayleigh-Jeans' Law.

This other formula is inversely proportional to ##λ^4##.

Hyperphysics covers the development of this ##\frac{1}{λ^4}## formula:
http://hyperphysics.phy-astr.gsu.edu/hbase/quantum/rayj.html

In it is written:
Rod Nave said:
...becoming a very good approximation when the size of the cavity is much greater than the wavelength as in the case of electromagnetic waves in finite cavity.
At low temperatures, a blackbody radiates more strongly in longer wavelengths.

Does this model indicate that Planck's law breaks down when the temperature is low and the size of the blackbody cavity is small?
 
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The Planck's law won't break down, no matter what.

EDIT: Well, as one case from the below comments, it can be violated, as soon as the underlying assumptions do not hold.
 
Last edited:
dextercioby said:
The Planck's law won't break down, no matter what.
The Plank's law is violated in led bulbs.
 
tade said:
Does this model indicate that Planck's law breaks down when the temperature is low and the size of the blackbody cavity is small?
No. A cavity is only an approximation of an ideal blackbody described by Planck's law. The approximation is what's breaking down here; it doesn't work when the cavity is too small.
 
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Nugatory said:
No. A cavity is only an approximation of an ideal blackbody described by Planck's law. The approximation is what's breaking down here; it doesn't work when the cavity is too small.
Got it. Are there any formula(s) that experimental physicists use when measuring the spectra of tiny cavities?
 
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tade said:
Does this model indicate that Planck's law breaks down when the temperature is low and the size of the blackbody cavity is small?
One of the assumptions in the derivation of the Planck's law is that the spectrum of possible energies is continuous. But the spectrum of an atom at rest is certainly not continuous. Nevertheless, the spectrum of realistic materials is usually quasi-continuous, i.e. discrete but with such a small energy spacing that this looks negligible. However, when the temperature is low and cavity small, then it is no longer negligible, the spectrum cannot longer be considered quasi-continuous, so the Plank's law becomes badly violated.
 
Demystifier said:
One of the assumptions in the derivation of the Planck's law is that the spectrum of possible energies is continuous. But the spectrum of an atom at rest is certainly not continuous. Nevertheless, the spectrum of realistic materials is usually quasi-continuous, i.e. discrete but with such a small energy spacing that this looks negligible. However, when the temperature is low and cavity small, then it is no longer negligible, the spectrum cannot longer be considered quasi-continuous, so the Plank's law becomes badly violated.
How small and cold does a cavity have to be before it starts deviating from Planck's law significantly?
 

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