Calculate the work in Joules by the Acetylene gas

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SUMMARY

The discussion centers on calculating the work done in Joules by Acetylene gas (C2H2) during its reaction with water at 298K and atmospheric pressure. The correct formula for calculating work in this isothermal gas expansion scenario is w = -nRT ln(P2/P1), where P1 is atmospheric pressure and P2 is derived from the ideal gas law. The participants clarify that the initial suggestion to use volumes in the work formula was incorrect, emphasizing the need to focus on pressure ratios instead. The heat of reaction is also mentioned as a separate consideration, not required for this specific calculation.

PREREQUISITES
  • Understanding of the ideal gas law (PV=nRT)
  • Knowledge of isothermal processes in thermodynamics
  • Familiarity with the concept of work in thermodynamic systems
  • Basic stoichiometry for calculating moles from mass
NEXT STEPS
  • Study the derivation and application of the work formula for isothermal gas expansions
  • Learn about calculating the heat of reaction for chemical processes
  • Explore the implications of pressure changes on gas behavior using the ideal gas law
  • Review examples of thermodynamic cycles involving gases to understand practical applications
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Chemistry students, particularly those studying physical chemistry, thermodynamics, and anyone involved in chemical engineering or related fields seeking to understand gas behavior in reactions.

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Homework Statement


A quantity of 4.50 g CaC2 is reacted with an excess of water at 298K and atmospheric pressure.
CaC2 (s) + 2 H2O (l) --> Ca(OH)2 (aq) + C2H2 (g)
Calculate the work done in Joules by the Acetylene gas against the atmospheric pressure.[/B]

Homework Equations


After asking my PChem professor, he said the I should use the work formula for an isothermic gas expansion, w= -nRT ln(V2/V1)
also for an isothermic expansion, q=-w[/B]

The Attempt at a Solution


P= 1 atm, n= 0.0702 mol R= 8.314 J/mol*K
I easily found the mole of the gas (0.0702), but my biggest problem is what are the volumes that are supposed to be used here? Using the moles of an ideal gas (22.4 L/mol), I found that the volume of the acetylene gas is 1.572 L, but I don't have a second volume to complete the equation. I feel like I'm missing something important, but I can't figure it out.[/B]
 
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ThymeSeer said:
at 298K and atmospheric pressure.
ThymeSeer said:
against the atmospheric pressure.
Can you recall another isothermal work process?
 
OH!
w= -nRT ln (P2/P1)

So the P1 is atmospheric pressure and for the P2 I use PV=nRT
Then I have both pressures and it's just plug and chug from there.
 
No, it's all at atmospheric.
 
Did your professor really say that you should use the work formula for an isothermic gas expansion, w= -nRT ln(V2/V1)
also for an isothermic expansion, q=-w?

Neither of these suggestions is correct.

Bystander is totally correct. Also, you weren't asked for the amount of heat transferred. But, if you did have to find it, you would be looking for the "heat of reaction," for the reaction under consideration.

Chet
 

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