Calculate Total Energy Required to Melt 100g of Lead

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Discussion Overview

The discussion centers on calculating the total energy required to melt 100g of lead, involving concepts of specific heat capacity, molar enthalpy of fusion, and temperature changes. The scope includes mathematical reasoning and application of thermodynamic principles.

Discussion Character

  • Mathematical reasoning, Homework-related

Main Points Raised

  • One participant presents the specific heat capacity of solid lead, the molar enthalpy of fusion, and the melting point, initiating the calculation process.
  • Another participant encourages the first to define the variables involved in the calculations, such as q, m, c, deltaT, n, and deltaH.
  • A participant calculates the heat required to raise the temperature of lead to its melting point using the formula q = mc(deltaT), arriving at a value of 4.8x10^3 J.
  • The same participant then calculates the energy required to melt the lead using q = n(deltaH), finding a value of 2.4 kJ.
  • The participant expresses uncertainty about whether to combine the two energy values and which units to use for the final result.
  • Another participant suggests that the user can choose to express the final energy in either kJ or J, or both, depending on the preferences of their instructor.
  • The original poster expresses frustration about not knowing if their calculations are correct but appreciates the assistance provided.

Areas of Agreement / Disagreement

Participants engage in a collaborative effort to solve the problem, but there is no consensus on the final expression of the total energy or the correctness of the calculations, as the original poster remains uncertain.

Contextual Notes

There are unresolved aspects regarding the combination of energy values in different units and the correctness of the calculations performed.

atOnz
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The specific heat capacity of solid lead is 0.159J/g°C, the molar enthalpy of fusion is 5.0kJ/mol, and the melting point of lead is 328°C. Calculate the total energy required to change 100g of lead at 25°C to molten lead at it's melting point.

I don't even know where to start, I know q=mc(delta)t and q=n(delta)H but I don't know which to use or when.
 
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atOnz said:
(snip)I know q=mc(delta)t and q=n(delta)H but I don't know which to use or when.

At least make a stab at it --- what's q? m? c? deltaT? n? deltaH? Look at the definitions of those quantities.
 
Fair enough, the least I can do is try it. Basically I will find the heat required to bring the lead to it's melting point using q = mc(delta)t.
So, q = (100g)(0.159/J/g°C)(328°C-25°C)...
q = 4.8x10^3 J.

After finding that out I need to find the energy required to actually melt the lead and change it's form from solid to a liquid. I would use q = n(delta)H.

n = the amount of moles per the 100g given. So 100g / 207.2g/mol = 0.483mol.

q = (0.483mol)(5.0kJ/mol) = 2.4kJ.
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So I have some numbers, and I assume that I add the two together. If I do infact have to do this, which unit (kJ or J) should I express it in?
 
atOnz said:
(snip)So I have some numbers, and I assume that I add the two together. If I do infact have to do this, which unit (kJ or J) should I express it in?

See? Not so hard was it? Units? Pick one, or use both --- delH, or q, = x.yzx kJ, or xyzx J. If you've got an obsessive-compulsive, anal-retentive teacher, use whatever you've been told --- "both" usually keeps such people happy.
 
Haha alright. I'd normally follow your "obsessive-compulsive, anal-retentive teacher" advice but this is the first set of work I've passed into him, and he has yet to say what he preferrs.

It's not that I can't do the work, it's that I hate not knowing if I'm right or wrong or even in the same ball park.

Thank you for your help!

-Jay
 

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