Why is ΔH°rxn -1172 kJ for This Reaction?

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SUMMARY

The reaction enthalpy change (ΔH°rxn) for the reaction 4NH3 (g) + 5O2 (g) → 4NO (g) + 6H2O (l) is calculated to be -1172 kJ. This value is derived using the formula ΔH°rxn = ΔH°products - ΔH°reactants, where the enthalpy of formation (ΔH°f) for O2 is defined as zero. The confusion regarding the inclusion of ΔH°f values for NO2 and HNO3 arises from irrelevant data provided in the problem statement, which does not affect the calculation.

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Homework Statement



Given the data in the table below, ΔH°rxn for the reaction

4NH3 (g) + 5O2 (g) → 4NO (g) + 6H2O (l)

is ________ kJ.

Substance ΔH∘f(kJ/mol)
H2O (l) -286
NO (g) 90
NO2 (g) 34
HNO3 (aq) -207
NH3 (g) -46

Homework Equations



ΔH°rxn = ΔH°products - ΔH°reactants

The Attempt at a Solution



ΔH°rxn = [(4x90)+(6x-286)] - [(4x-46)+(X)]

ΔH°rxn = (-1356) - (-184+X)

ΔH°rxn = -1356 + 184 - X

ΔH°rxn = -1172 + X

At first I selected, D.) The ΔH°f of O2 (g) is needed for the calculation.
However, apparently the answer is -1172, but I have no idea why. How can -1172 be the answer here? And why do they give me the enthalpy of formation for NO2 and HNO3 if neither of those compounds are in my reaction?
 
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Okay, I just realized the ΔH°f of O2 is defined to be zero...
Now it all makes sense.
 
Drakkith said:
I just realized the ΔH°f of O2 is defined to be zero...

And you answer - that it is needed - wasn't wrong in general. Defining ΔH°f of O2 as zero means you know its value ;)
 
Drakkith said:
And why do they give me the enthalpy of formation for NO2 and HNO3 if neither of those compounds are in my reaction?
why?
 
Either to confuse him, or because it was copy/pasted from another problem and someone didn't bother to leave just what is important for the question.
 

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