Calculating Heat Capacity of Calorimeter

Click For Summary
SUMMARY

The discussion centers on calculating the heat capacity of a calorimeter using a sample of fructose (C6H12O6) with a mass of 0.900 g. The calorimeter was calibrated with a 500 W heating tape, resulting in a temperature increase of 5 K over 100 seconds. The correct calculation for the heat capacity involves multiplying the power (500 W) by the time (100 s) to obtain 50,000 J, then dividing by the temperature change (5 K), yielding a heat capacity of 10,000 J/K. The final heat capacity does not require multiplication by the temperature rise of 1.4 K, as the question specifically asks for the calorimeter's heat capacity.

PREREQUISITES
  • Understanding of calorimetry principles
  • Knowledge of heat capacity definitions
  • Familiarity with units of power (Watts) and energy (Joules)
  • Basic algebra for manipulating equations
NEXT STEPS
  • Study the concept of heat capacity in thermodynamics
  • Learn about calorimetry experiments and their applications
  • Explore the relationship between energy, power, and temperature change
  • Investigate different methods for calibrating calorimeters
USEFUL FOR

Chemistry students, laboratory technicians, and educators involved in thermodynamics and calorimetry experiments will benefit from this discussion.

Armitage12
Messages
9
Reaction score
0
Need a little help, as I seem to have gotten confused.
Looking over past exam questions for the heat capacity of a calorimeter, this one is the one I am looking at :


A sample of the sugar fructose (C6H12O6) of mass 0.900 gwas placed in a calorimeter and
ignited inthe presence of excess oxygen, at the saturation vapour pressure of water and at
constant volume.The temperature rose by 1.4 K.
The calorimeter had previously been calibrated by passing an electrical current through a heating
tape for 100 s. The power supplied to the tape was 500 W and the temperature of the calorimeter
rose by 5 K


Right. The reason I am confused, is the textbook I've been reading from had similar worked examples, however they didn't have any values in watts. They have in Ampere and Volts.
As far as I am aware 1 watt is equal to 1j/s..


So to work the heat capacity of the calorimeter,
would i:


1) 500W*60 to get to 8.3 J/s
2) then multiply by 100s and divide by the 5K.
3) then multiply this answer by 1.4k, to get 233.3 joules.
4) Finally, divide by 1000, to get the heat capacity of the calorimeter at 0.23KJ?


Or am I way off?
 
Physics news on Phys.org
Armitage12 said:
Or am I way off?
Waayyy ooblackf.
Armitage12 said:
heating tape for 100 s
This is a clue.
Armitage12 said:
500 W
This is another clue. Hint, what's "Watt" mean, what are the units?
Armitage12 said:
rose by 5 K
Then, divide.
 
The units of W is one Joule per second?, so If i multiply the 500W by the 100s. I get 50000 J?
Do I then divide this by the 5K? Finally multiply by the 1.4k? to get the final answer at 14Kj?
 
Bystander said:
Waayyy ooblackf.

This is a clue.

This is another clue. Hint, what's "Watt" mean, what are the units?

Then, divide.

Armitage12 said:
The units of W is one Joule per second?, so If i multiply the 500W by the 100s. I get 50000 J?
Do I then divide this by the 5K? Finally multiply by the 1.4k? to get the final answer at 14Kj?

Or do I need not multiply by the 1.4k.

Is it simply 500w x 100s/ 5k= 10,000J/1000= 10kJ??
 
Why so uncertain?
Armitage12 said:
answer at 14Kj
Upper case "K" denotes Kelvin, or degrees Kelvin (same size as C); you'll want lower case "k" to denote "kilo" or thousand; lower case "j" has a number of meanings, but none indicate Joule, or upper case "J." Other than that, you're in business.
 
Armitage12 said:
Or do I need not multiply by the 1.4k.
Now I know why you're uncertain. What's the definition of "heat capacity?"
 
Bystander said:
Now I know why you're uncertain. What's the definition of "heat capacity?"

The amount of heat needed to raise the temperature of an object or substance by 1 degree.. So I don't need to multiply by 1.4k at the end?
Just 500W x 100s/5k= Heat capacity of Calorimeter? so 10 kJ?

Sorry its been a long day haha.
 
Armitage12 said:
heat needed to raise the temperature of an object or substance by 1 degree
Think. What are the units? You multiplied watts by seconds and got joules. If you divide joules by temperature, what do you get for units?
 
I would of assumed J/K?
 
  • #10
Yes. Now, you know the heat capacity of the calorimeter. You know the temperature rise for a particular measurement. How do you calculate the heat released in that measurement?
 
  • #11
Bystander said:
Yes. Now, you know the heat capacity of the calorimeter. You know the temperature rise for a particular measurement. How do you calculate the heat released in that measurement?

So now I just multiply it by the 1.4K? to get the amount of heat released as I had it in J/K. So as it was in Joules per kelvin, if i times by 1.4 Kelvin, the heat will adjust, so I will know how much?

But the question was only asking for the heat capacity of the calorimeter? not how much heat was released? So I am right in assuming, that for just the heat capacity of the calorimeter, I don't need to multiply by the 1.4K?
 
  • #12
Correct.
 
  • #13
Bystander said:
Correct.
You were a massive help, really appreciate it!
 

Similar threads

  • · Replies 6 ·
Replies
6
Views
2K
Replies
3
Views
2K
Replies
5
Views
4K
Replies
2
Views
2K
  • · Replies 2 ·
Replies
2
Views
3K
  • · Replies 3 ·
Replies
3
Views
3K
  • · Replies 10 ·
Replies
10
Views
4K
  • · Replies 3 ·
Replies
3
Views
4K
Replies
3
Views
4K
Replies
1
Views
2K