Calculating Internal Energy of Solid CO2: How to Obtain Thermodynamic Values?

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SUMMARY

The discussion centers on the challenges of obtaining thermodynamic values for solid CO2, specifically internal energy and entropy, using tools like REFPROP (by NIST) and EES. Both tools lack data below 212K, despite CO2 sublimating at approximately 195K at one atmosphere. Participants emphasize the importance of understanding specific heat capacity and latent heat for solid CO2, highlighting a gap in available thermodynamic data for this state.

PREREQUISITES
  • Understanding of thermodynamic principles, particularly phase changes.
  • Familiarity with REFPROP (NIST) for thermodynamic property calculations.
  • Knowledge of EES (Engineering Equation Solver) for energy analysis.
  • Basic concepts of specific heat capacity and latent heat.
NEXT STEPS
  • Research methods for calculating internal energy and entropy for solid CO2.
  • Explore alternative databases or resources for thermodynamic properties of solid CO2.
  • Learn about the phase change properties of CO2 and their implications in thermodynamics.
  • Investigate the limitations of REFPROP and EES in low-temperature thermodynamic data.
USEFUL FOR

This discussion is beneficial for thermodynamic analysts, chemical engineers, and researchers focusing on the properties of CO2 in solid state, as well as those seeking to enhance their understanding of phase transitions and thermodynamic calculations.

hymeme
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I am doing a simple thermodynamic analysis. Couldn't get thermodynamic values (such as internal energy, exergy, and so on) from common data base of CO2. I looked it up in REFPROP(By NIST) and EES. None of them have data below 212K. At one atmosphere CO2 sublime at about 195K.
Could anyone explain this to me? How to calculate the internal energy and entropy when CO2 is in solid stae?
Thank you very much!
 
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Thank you very much! I felt that it is kind strange that the properties of solid state are not included.
 

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