Calculating S-F Bond Energy in SF6 using Standard Heat of Formation Values

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SUMMARY

The discussion focuses on calculating the average S-F bond energy in sulfur hexafluoride (SF6) using standard heat of formation values. The standard heat of formation values provided are -1100 kJ/mol for SF6(g), 275 kJ/mol for S(g), and 80 kJ/mol for F(g). The correct approach involves using the equation ∆H = ∆Hf (products) - ∆Hf (reactants) and recognizing that the total bond energy must account for all six S-F bonds in SF6. The average bond energy is derived from the total enthalpy change divided by the number of bonds formed.

PREREQUISITES
  • Understanding of thermodynamics and enthalpy changes
  • Familiarity with standard heat of formation values
  • Knowledge of chemical bonding and bond energy concepts
  • Ability to perform stoichiometric calculations in chemical reactions
NEXT STEPS
  • Review the concept of bond energy and its calculation methods
  • Study the application of Hess's Law in thermochemical calculations
  • Learn about the relationship between bond energies and molecular stability
  • Explore advanced topics in thermodynamics, such as Gibbs free energy
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Chemistry students, educators, and professionals involved in thermodynamics and molecular chemistry who seek to deepen their understanding of bond energy calculations in complex molecules like SF6.

harambe
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Homework Statement


Estimate the average S-F bond energy in SF6 The standard heat of formation values of SF6(g) , S(g) and F)(g) are: -1100, 275 and 80 kj / mol respectively.

Homework Equations


∆H=∆Hf (products) -∆Hf(Reactants)

S(g) +6F)(g) ------>SF6(g)

The Attempt at a Solution



I found the ∆H formation of the reaction which I got -1455 kJ/ mol and taking this as my bond energy. But My answer doesn't match so can you tell me what am I doing wrong [/B]
 
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harambe said:
I found the ∆H formation of the reaction which I got -1455 kJ/ mol and taking this as my bond energy.

That would be true for a molecule with SF formula.
 
First, your calculation of ∆H is wrong; you have only taken account of one F. Second, how many S-F bonds are formed in the reaction? How do you work out the average energy per bond? Third, bond energy is the energy released by forming a bond, or the energy consumed by breaking a bond - it is a positive quantity. How is it related to ∆H?
 
mjc123 said:
First, your calculation of ∆H is wrong;
Yes, -1455kJ/mol is not the right answer.

Harambe, you need to answer questions like: how many bonds thee are in the reagents, how many bonds there are in the products... also the request energy is only for 1 bond.
 

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