Calorimetry - finding the final temperature of a system of ice and water

Click For Summary
SUMMARY

The discussion focuses on the calculation of the final temperature in a calorimetry problem involving ice and water. The key equations used are Q=mL for the melting ice and Q=mc(change in T) for the cooling water. A significant issue arises from the incorrect application of the specific heat capacity of water, which is 4.186 J/g, not per kilogram. The participants emphasize the importance of unit consistency and proper conversions between Celsius and Kelvin to avoid calculation errors.

PREREQUISITES
  • Understanding of calorimetry principles
  • Familiarity with specific heat capacity calculations
  • Knowledge of unit conversions between Celsius and Kelvin
  • Ability to solve algebraic equations
NEXT STEPS
  • Research the concept of specific heat capacity and its units
  • Learn about unit conversion techniques between different temperature scales
  • Explore advanced calorimetry problems involving phase changes
  • Practice solving algebraic equations related to thermal energy transfer
USEFUL FOR

Students studying thermodynamics, physics educators, and anyone involved in calorimetry experiments or thermal energy calculations.

JoeyBob
Messages
256
Reaction score
29
Homework Statement
See attached
Relevant Equations
Q=mL

Q=mc(change T)
So all of the ice melts and I am guessing it then warms some so

Q=mL+mc(change in T)

for the water that cools down

Q=mc(change in T)

Q_cold = -Q_hot so -mc(Tf - Ti) = mL+mc(Tf - Ti)

My issue is that I have 2 unknowns. I don't know the specific heat capacity of water and I don't know the final temperature. I am not sure how I can find another equation to find the specific heat capacity of water either.

Even when I look up the specific heat capacity of water I am left with the wrong answer. specific heat capacity of water from internet is 4.186 J. When I use this I get -19346, which is obviously wrong. So I don't know if I am doing the equations wrong or if I need to find the specific heat capacity somehow.
 

Attachments

  • question.PNG
    question.PNG
    14.2 KB · Views: 164
Physics news on Phys.org
JoeyBob said:
Homework Statement:: See attached
Relevant Equations:: Q=mL

Q=mc(change T)

specific heat capacity of water from internet is 4.186 J.
What units do you need it into match the other given numbers?
 
Please tell me you didn’t use the same value for Ti for water and ice.
 
Chestermiller said:
Please tell me you didn’t use the same value for Ti for water and ice.
I'm pretty sure it's a units conversion issue.
 
  • Like
Likes   Reactions: JoeyBob
haruspex said:
What units do you need it into match the other given numbers?
What I was doing was converting Celsius to kelvin then converting it back into Celsius after I was done. Heres the link to the calculator I was using to check my algebra with the numbers plugged in. Probably easier to read but ill also type it out here.

https://www.symbolab.com/solver/algebra-calculator/-21.3\cdot4.186\left(x-346.95\right)=7.1\cdot334000+7.1\cdot4.186\cdot\left(x-273.15\right)

-21.3 kg * 4.186 J * (x-346.95 K) = 7.1 kg * 334000 J/kg + 7.1 kg * 4.186 J * (x-273.15)

The part on the left is of the relatively hot liquid water (mc(Tf-Ti)) where the part on the right is of the ice where it melts (mL+mc(Tf-Ti)).

As you can see I use their different masses and different initial temperatures for each.
 
JoeyBob said:
What I was doing was converting Celsius to kelvin then converting it back into Celsius after I was done. Heres the link to the calculator I was using to check my algebra with the numbers plugged in. Probably easier to read but ill also type it out here.

https://www.symbolab.com/solver/algebra-calculator/-21.3\cdot4.186\left(x-346.95\right)=7.1\cdot334000+7.1\cdot4.186\cdot\left(x-273.15\right)

-21.3 kg * 4.186 J * (x-346.95 K) = 7.1 kg * 334000 J/kg + 7.1 kg * 4.186 J * (x-273.15)

The part on the left is of the relatively hot liquid water (mc(Tf-Ti)) where the part on the right is of the ice where it melts (mL+mc(Tf-Ti)).

As you can see I use their different masses and different initial temperatures for each.
That 4.18 is per gram, not per kilogram.
 
Chestermiller said:
That 4.18 is per gram, not per kilogram.
Yeah I think that explains it. When I look up specific heat capacity of water 4.186 joules is in bold. You have to read below to see 4.186 J/g. Idk why the correct units arent displayed initially.
 
JoeyBob said:
-21.3 kg * 4.186 J * (x-346.95 K) = 7.1 kg * 334000 J/kg + 7.1 kg * 4.186 J * (x-273.15)
Take a good look at all those units.
On the left you have kg*J*K.
First term on the right is kg*J/kg = J (so that one is right).
Second term on the right you show as kg*J.
 
  • Like
Likes   Reactions: JoeyBob

Similar threads

Replies
12
Views
1K
  • · Replies 6 ·
Replies
6
Views
610
  • · Replies 17 ·
Replies
17
Views
6K
  • · Replies 3 ·
Replies
3
Views
2K
  • · Replies 11 ·
Replies
11
Views
5K
  • · Replies 2 ·
Replies
2
Views
798
  • · Replies 9 ·
Replies
9
Views
5K
  • · Replies 3 ·
Replies
3
Views
2K
  • · Replies 5 ·
Replies
5
Views
6K
  • · Replies 7 ·
Replies
7
Views
2K