Calorimetry - finding the final temperature of a system of ice and water

AI Thread Summary
The discussion revolves around calculating the final temperature of a system involving ice and water using calorimetry equations. The user is struggling with two unknowns: the specific heat capacity of water and the final temperature. They initially used the specific heat capacity value of 4.186 J, but confusion arose regarding its units, as it is actually 4.186 J/g rather than per kilogram. The conversation highlights the importance of unit consistency in calculations, emphasizing that the specific heat capacity must be applied correctly to avoid erroneous results. Ultimately, the issue appears to stem from a misunderstanding of unit conversions and the proper application of calorimetry formulas.
JoeyBob
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Homework Statement
See attached
Relevant Equations
Q=mL

Q=mc(change T)
So all of the ice melts and I am guessing it then warms some so

Q=mL+mc(change in T)

for the water that cools down

Q=mc(change in T)

Q_cold = -Q_hot so -mc(Tf - Ti) = mL+mc(Tf - Ti)

My issue is that I have 2 unknowns. I don't know the specific heat capacity of water and I don't know the final temperature. I am not sure how I can find another equation to find the specific heat capacity of water either.

Even when I look up the specific heat capacity of water I am left with the wrong answer. specific heat capacity of water from internet is 4.186 J. When I use this I get -19346, which is obviously wrong. So I don't know if I am doing the equations wrong or if I need to find the specific heat capacity somehow.
 

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JoeyBob said:
Homework Statement:: See attached
Relevant Equations:: Q=mL

Q=mc(change T)

specific heat capacity of water from internet is 4.186 J.
What units do you need it into match the other given numbers?
 
Please tell me you didn’t use the same value for Ti for water and ice.
 
Chestermiller said:
Please tell me you didn’t use the same value for Ti for water and ice.
I'm pretty sure it's a units conversion issue.
 
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haruspex said:
What units do you need it into match the other given numbers?
What I was doing was converting Celsius to kelvin then converting it back into Celsius after I was done. Heres the link to the calculator I was using to check my algebra with the numbers plugged in. Probably easier to read but ill also type it out here.

https://www.symbolab.com/solver/algebra-calculator/-21.3\cdot4.186\left(x-346.95\right)=7.1\cdot334000+7.1\cdot4.186\cdot\left(x-273.15\right)

-21.3 kg * 4.186 J * (x-346.95 K) = 7.1 kg * 334000 J/kg + 7.1 kg * 4.186 J * (x-273.15)

The part on the left is of the relatively hot liquid water (mc(Tf-Ti)) where the part on the right is of the ice where it melts (mL+mc(Tf-Ti)).

As you can see I use their different masses and different initial temperatures for each.
 
JoeyBob said:
What I was doing was converting Celsius to kelvin then converting it back into Celsius after I was done. Heres the link to the calculator I was using to check my algebra with the numbers plugged in. Probably easier to read but ill also type it out here.

https://www.symbolab.com/solver/algebra-calculator/-21.3\cdot4.186\left(x-346.95\right)=7.1\cdot334000+7.1\cdot4.186\cdot\left(x-273.15\right)

-21.3 kg * 4.186 J * (x-346.95 K) = 7.1 kg * 334000 J/kg + 7.1 kg * 4.186 J * (x-273.15)

The part on the left is of the relatively hot liquid water (mc(Tf-Ti)) where the part on the right is of the ice where it melts (mL+mc(Tf-Ti)).

As you can see I use their different masses and different initial temperatures for each.
That 4.18 is per gram, not per kilogram.
 
Chestermiller said:
That 4.18 is per gram, not per kilogram.
Yeah I think that explains it. When I look up specific heat capacity of water 4.186 joules is in bold. You have to read below to see 4.186 J/g. Idk why the correct units arent displayed initially.
 
JoeyBob said:
-21.3 kg * 4.186 J * (x-346.95 K) = 7.1 kg * 334000 J/kg + 7.1 kg * 4.186 J * (x-273.15)
Take a good look at all those units.
On the left you have kg*J*K.
First term on the right is kg*J/kg = J (so that one is right).
Second term on the right you show as kg*J.
 
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