Can a ground state energy be negative?

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SUMMARY

The ground state energy can indeed be negative, as demonstrated by the example of five energy values: -25 eV, -5 eV, 0 eV, 5 eV, and 25 eV. In this case, -25 eV represents the lowest energy state, confirming that the ground state is defined by the lowest energy value rather than its absolute value. The significance lies in energy differences rather than the numerical values themselves, allowing for arbitrary definitions of energy levels without affecting the system's behavior.

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Just a short question.

I have five energies.

-25 eV
-5 eV
0 eV
5 eV
25 eV

The textbook definition is that the ground state is the state with the lowest energy, i.e. I believe 0 in this case.

But that is taking the absolute value of theenergies.

In reality the lowest energy is -25 eV so is it instead actually the -25 eV in this case
 
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Yes, energies can be negative, so -25eV is the correct answer. The way that energy is defined, it's not really the numerical value of the energy that is important (it's completely arbitrary), but it's the energy differences that matter. So, you could define the five energies as 0, 20, 25, 30, and 50eV and the system would pretty much be the same (although you could not compare these energies measured from a system using a different reference point).
 

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