The discussion centers on a homework question regarding the potential energy of a pair of charges, specifically asking if it can be expressed in volts. It clarifies that electric potential (volts) is defined as potential energy per unit charge, leading to the equation U = qV, which results in energy measured in joules. Participants argue that it is incorrect to express energy in volts, as volts represent electric potential, not energy. Some suggest that the question likely contains a typo and should specify joules instead. Ultimately, the consensus is that while volts and joules are related, potential energy should not be directly expressed in volts.