Can UV Light Cause Electrons to Eject from a Metal Surface?

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SUMMARY

The discussion centers on the photoelectric effect, specifically how UV light can eject electrons from a metal surface. It is established that each metal has a unique work function, which is the minimum energy required to release an electron. Einstein's photoelectric equation, KE = hf - W, illustrates that the kinetic energy of emitted electrons increases with the frequency of incident photons, provided the frequency exceeds the threshold. The conversation also clarifies that while electrons can only absorb specific frequencies for excitation, once ionized, they can absorb any excess energy, leading to varying kinetic energies of emitted electrons.

PREREQUISITES
  • Understanding of the photoelectric effect and Einstein's photoelectric equation.
  • Familiarity with concepts of work function and kinetic energy in quantum mechanics.
  • Knowledge of electron band structure in metals and how it relates to photoemission.
  • Basic principles of quantum mechanics, particularly regarding photon interactions with electrons.
NEXT STEPS
  • Study the detailed implications of Einstein's photoelectric equation in various materials.
  • Explore the concept of electron band structure and its impact on photoemission techniques.
  • Research the differences between classical and quantum mechanical models of light and matter interactions.
  • Investigate experimental setups for measuring photoemission and analyzing electron energy spectra.
USEFUL FOR

Students and researchers in physics, particularly those focused on quantum mechanics, material science, and photonics, will benefit from this discussion on the photoelectric effect and its underlying principles.

raymes_k
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when UV light is shone upon a metal, can electrons be ejected from the metal or does this only occur if there is another force in play (eg a potential difference to sweep the elctrons away)

also, if electrons (at their base energy level) only accept a specific frequency of UV light (which varies from element to element) [<correct me if i wrong here], then how come when you increase the frequency of UV light on a surface, we observe an increase in an emitted electrons total energy (ie, the electrons still absorbed the the EM radiation)
 
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Electrons can be ejected, but without an accelerating PD they won't travel very far!

Einsteins photoelectric equation tells us that any 'spare' energy left over after ionisation is given as Kinetic energy. Hence, as the energy of incident photons increases, so does the emitted electrons KE.

Each metal has a so called 'work function' which is the energy needed to eject an electron, so yes, each element will have a different value.
 
however i was also under the impression (from my teacher) that individual electrons can only accept a specific frequency of radiation at different quantum levels (ie, at their base level they may, for example, only be able to accept one frequency of UV light). How does this explain the fact that, whether it be a high or low frequency radiation shining on them (above the threshold), we still observe them being ejected from the metal (with different KE of course)
 
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ummm this effect happens only one photon (light particle, in this case light behave like a particle, but although overall it's a wave) <--- help me explaine more

only one photon can knock one electron from the metal. energy of photon is "qutan" that is in packets or different level but not continouse building up.

you either use one photon kick out one elctron but not two half photon.

different frequency can give different energy to phton enable to kick out one electron.

it also define ke= hf-W w=work force for each metal. h = contant f= frequency.
 
raymes_k said:
however i was also under the impression (from my teacher) that individual electrons can only accept a specific frequency of radiation at different quantum levels (ie, at their base level they may, for example, only be able to accept one frequency of UV light). How does this explain the fact that, whether it be a high or low frequency radiation shining on them (above the threshold), we still observe them being ejected from the metal (with different KE of course)

Accepting only specific energies (or frequencies) is true for excitation. Once you have enough energy to ionize the electron, any energy can be absorbed. The free electron energies are not quantized, only the bound state energies.
 
As swansont has mentioned, the conduction electrons (which are involved in most elementary photoemission experiments) has a continuous energy band. If the photon you use has an energy just barely equal to the work function, then you will, in principle, get only photoelectrons with a very narrow range of energy. However, if you can do that, I have an accelerator photoinjector that I want you to work at! :)

Most of the time, your photons are at some energy significantly above the work function. What happens in this case is that a single photon can cause the emission of electron from the top of the conduction band to an energy h\nu - \Phi below the top of the conduction band. This whole range of the conduction band is available to the photon to excite an electron into the vacuum state.

So the energy spectrum of the photoelectrons is not really a function of simple photoelectric effect experiment in the Einstein model, but rather a direct reflection of the band structure of the material being used. That is why such an experiment, nowadays called photoemission, is such a valuable technique in studying the band properties of materials.

Zz.
 
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I've got some itches concerning the analysis of the photoelectric effect...

First,
One very good thing about this experiment is that the difference between classical and QM prediction is very distinct and fairly easy to understand. It's always like .. "If light was a wave, then this and this would happen.. and if light was a particle, this and this would happen .." ... But there is a hidden assumption here that's never presented, namely that the waves are sinusodial. Am I wrong in saying that classical physics had no model for atomic EM emission? So what were they basing this assumption on? What natural nano-wavelength source has charges oscillating in such a specific way as to produce multiple continuous sinusodial waves with different wavelengths ? - answer: None. It's not possible.

Second,
In classical physics the process of emission and absorption isn't as easy as it's pictured in QM. A wave doesn't simply hit a particle, transfer all it's energy, and then disappear. What % of the total energy a wave transferes is very dependent on the "size difference" between the wave and the particle. Ironically, Heisenbergs thought experiment with the microscope explains this well.
Radio is another example where this wave/receiver relationship is important.
 
*scratch* *scratch*
 

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