Can you gold plate a penny using gold nitrate?

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Discussion Overview

The discussion revolves around the feasibility of gold plating a penny using gold nitrate or other methods, including electroplating and electroless gold. Participants explore various chemical approaches, potential hazards, and alternative plating options such as silver plating.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant inquires about using gold nitrate for gold plating without melting gold, questioning its rarity, expense, and safety.
  • Another suggests electroplating as a method, noting the need for a strong acid to dissolve gold and mentioning gold chloride as a potential alternative.
  • Electroless gold is proposed as an effective method for gold plating.
  • Concerns are raised about achieving a lustrous gold cover, with one participant explaining that low concentrations of gold ions are necessary, but that cyanidic gold complexes are toxic.
  • A participant shifts the focus to silver plating, asking if silver nitrate could be used similarly and referencing a crystal growth experiment with copper wire.
  • Historical context is provided regarding the use of silver nitrate and formaldehyde for making mirrors.
  • Another participant notes that silver plating is easier but requires reducing the concentration of free silver ions to achieve a lustrous finish, suggesting a method involving silver chloride and salt.
  • A participant shares a link to a diffusion simulation program that illustrates how deposition parameters affect the structure of electrodeposited substances.
  • One participant suggests that silver plating may be necessary before gold plating to achieve optimal results.

Areas of Agreement / Disagreement

Participants express various methods and considerations for gold and silver plating, but there is no consensus on the best approach or the specifics of the chemical processes involved. Multiple competing views and techniques are presented without resolution.

Contextual Notes

Participants mention the toxicity of certain chemicals and the need for careful handling, but specific assumptions about the chemical processes and concentrations remain unresolved.

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Just like the experiment in high school using zinc powder and sodium hydroxide, is there a way to use real gold plating without having to melt real gold. Such as gold nitrate? Is gold nitrate rare, expensive or dangerous? Thanks!
 
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If you want to gold-plate a penny, you can do so by electroplating it. You will need a pretty strong acid to get the gold into solution, though, so you'll have to be cautious.

Edit: Gold chloride may be an acceptable salt for electroplating.
 
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Electroless gold works great for this. Google "electroless gold".
 
The problem is to obtain a lustrous cover of gold. To that end the effective concentration of gold has to be very low. One usually achieves this working with a solution of cyanidic gold complexes which release only very little gold ions. But these are very toxic.
 
Thanks a lot everyone for your insight. This helps a lot! What about silver plating? or Silver Nitrate? With the silver nitrate growing crystals on copper wire experiment could this be achieved with a small plating of silver on a penny in the same way or would it require diff chemicals?
 
Mirrors used to be made by plating silver onto glass using silver nitrate and formaldehyde. In the lab this is used in the "[URL Test for aldehydes.[/url]
 
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silver is much more easy. However, you have to reduce the concentration of free silver ions considerably to obtain a lustrous cover. This can be achieved simply by rubbing a penny with a mixture of salt and silverchloride. Silverchloride is ill soluble and the free chloride ions reduce the concentration of silver even further. You can even prepare the chloride in situ by mixing some silvernitrate with rocksalt while wetting.
 
This is slightly off topic, but you may find it amusing. Go to the page:

http://www.chembuddy.com/?left=all&right=download

scroll down and download diffusion simulation program. It nicely shows how structure of the electrodeposited substance depends on the deposition parameters. Basically it tells that the lower probability of the single ion reduction, the thicker and less spongy the deposit. This is in a way related to the low concentration givng nice, lustrous cover.
 
Last edited by a moderator:
You'd probably have to silver-plate it before gold-plating it to get the best result.
 

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