mheslep said:
Just curious: that's due only to the tritium atoms in the water? Not another source?
While the fuel in BWRs (and PWRs) is solid, all solid material has some miniscule amounts of diffusion. As such, some fission products get into the primary coolant, such as Iodine, Cesium, Xenon, and even Boron from the control rods. During normal operation, there are chemistry samples done, and the specific activity of all of these fission products are looked at, as the ratio of the different fission product decay chains is a sign of whether or not the fuel has failed (Cracked) or if it is just simple diffusion of fission products through the cladding material.
Tritium comes not just from hydrogen absorbing neutrons, but also from the boron in the control rods. The B-10 can absorb a neutron and then undergo double alpha decay, leaving behind a tritium atom. Any boron in primary coolant, or any tritium/boron that leaches out of the rods will also increase tritium inventory in the primary coolant.
In all reactors, when the reactor is online, the main source of radiation in the primary coolant loop is N-16. N-16 is a very short lived isotope (several seconds), and is virtually completely gone within a few minutes after shutdown. When the reactor is offline, cobalt-60 (which comes from stellite material in valve seats as well as on control rod blade rollers used for preventing the blades from rubbing the fuel material), Co-60 is the main gamma emitter when the reactor is offline, usually in the form of hot particles which get trapped in the reactor coolant system.tl;dr most of the fission products and decay chains make it into primary coolant, not just tritium.
Additionally, primary coolant in both BWRs and PWRs is radioactive. PWRs have more tritium because they use Boron as a chemical shim, while the only tritium in BWR coolant is that from neutron capture and leeching. BWRs do not have a secondary coolant loop, but PWRs do, and their secondary loop also has radioactive products in it. PWRs have drastically less, as only things which leech through the steam generator tubes or pass through tube leaks generally get into secondary coolant. Additionally, reclaimed rad-waste water (which is reprocessed for reactor or secondary use) may contain slight amounts of fission products which weren't removed in the rad waste system. Secondary cooling loops have rather large levels of tritium however (compared to BWRs) as well, because tritium does not get removed in the normal rad waste process, as it chemically looks the same as normal water, and rad waste processing is primarily chemical/resin/ion exchange based.