Confused about selection rules in optical transitions

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SUMMARY

This discussion centers on the selection rules for optical transitions between electronic levels in ions within a crystal, specifically referencing a paper that measures transitions involving quantum numbers J = 15/2, M_J = ±5/2, and J = 9/2, M_J = ±9/2. The transitions exhibit ΔJ = 3 and ΔM_J = 7, raising questions about the validity of these transitions given the mixing of electronic states. The participant highlights the potential for significant contributions from states with differing quantum numbers, despite the paper's focus on detecting weak axion signals and the use of a standard laser for excitation.

PREREQUISITES
  • Understanding of quantum mechanics, specifically angular momentum and selection rules.
  • Familiarity with electronic transitions in ions and their behavior in crystal fields.
  • Knowledge of axion physics and its implications for weak signal detection.
  • Experience with experimental techniques involving laser excitation of atomic states.
NEXT STEPS
  • Research the implications of crystal field theory on electronic transitions in ions.
  • Study the role of selection rules in quantum mechanics, particularly for optical transitions.
  • Explore experimental methods for detecting weak signals, such as those related to axion searches.
  • Investigate the effects of state mixing on transition probabilities in quantum systems.
USEFUL FOR

Physicists, particularly those specializing in quantum mechanics, condensed matter physics, and experimental particle physics, will benefit from this discussion, especially those involved in research on optical transitions and axion detection methods.

Malamala
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Hello! This question is motivated by this paper in particular (let me know if it is not open access). They measure transitions between electronic levels inside an ion, placed inside a crystal. In Fig. 2, they show measured transitions between 2 electronic levels, one of them having ##J = 15/2## and ##M_J=\pm 5/2## while the other one has ##J = 9/2## and ##M_J=\pm 9/2## which means that the transitions have ##\Delta J = 3## and, for the largest difference, ##\Delta M_J = 9/2 - (-5/2) = 7##. How is this possible? I understand that, ##J## and ##M_J## are not perfectly good quantum numbers due to the crystal field, but they are still quite good to a certain degree. Also, even if there is some mixing of other electronic states with different ##J## and ##M_J## values, I wouldn't expected states with so different quantum numbers to have a significant contribution to the mixing. Given that the paper claims to search for very weak axion signals, I assume the strategy is not to use highly forbidden transitions, on top of the fact that the signal sought for is very weak (but anyway, they seem to be able to easily excite these transitions with a normal laser). What am I missing here? Thank you!
 

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