Creation and annihilation operators

In summary, the book provides a comprehensive introduction to the principles of quantum mechanics, as they are applied to chemistry and chemical physics.
  • #1
LagrangeEuler
717
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In one dimensional problems in QM only in case of the potential ##V(x)=\frac{m\omega^2x^2}{2}## creation and annihilation operator is defined. Why? Why we couldn't define same similar operators in cases of other potentials?
 
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  • #2
LagrangeEuler said:
In one dimensional problems in QM only in case of the potential ##V(x)=\frac{m\omega^2x^2}{2}## creation and annihilation operator is defined. Why? Why we couldn't define same similar operators in cases of other potentials?

I guess mathematics wouldn't work and you would not be able to reduce those operators into entities with commutation operators leading to simple algebraic relations. Plus this harmonic potential corresponds to free fields, and this "freeness" i guess is the physical reason why things are simple and tractable and meaningful.
 
  • #3
Stepping operators can also be used to solve the Coulomb problem. Also the n-dimensional harmonic oscillator. In principle such operators always exist, but only in a few problems are they simple enough to write down in useful form.
 
  • #4
Bill_K said:
Stepping operators can also be used to solve the Coulomb problem. Also the n-dimensional harmonic oscillator. In principle such operators always exist, but only in a few problems are they simple enough to write down in useful form.


I suppose that. That they always could be written. But why we that speak about phonons only in that problem. Why we don't give a name of excited states in some other problem.

Stepping operators can also be used to solve the Coulomb problem.
Do you have reference for this?
 
  • #5
The stepping operators for the H atom form the generators of an SO(4) symmetry group, and are also related to its separability in parabolic coordinates. Here's a paper that talks about it.
 
  • #6
Also see the reference given in this earlier thread, post #2, courtesy of dextercioby.

The book itself is available online http://www.scribd.com/doc/22703322/Fitts-D-D-Principles-of-Quantum-Mechanics-As-Applied-to-Chemistry-and-Chemical-Physics.
 
Last edited:

What are creation and annihilation operators?

Creation and annihilation operators are mathematical operators used in quantum mechanics to describe the creation and destruction of particles. They are represented by the symbols a and a† respectively.

How do creation and annihilation operators work?

Creation operators act on a state to increase the number of particles present, while annihilation operators reduce the number of particles in a state. They can be used to create and destroy particles in a system, and their combination allows for the calculation of probabilities and expectation values.

What is the relationship between creation and annihilation operators?

Creation and annihilation operators are related to each other through their commutation relation [a, a†] = 1, where [x,y] represents the commutator of operators x and y. This relation allows for the creation and annihilation operators to be used in conjunction with each other in calculations.

How are creation and annihilation operators used in quantum field theory?

In quantum field theory, creation and annihilation operators are used to quantize fields and describe the creation and destruction of particles in a field. They are essential in the formulation of the second quantization method, which allows for the description of multiple particles in a system.

What are some applications of creation and annihilation operators?

Creation and annihilation operators have many applications, including in quantum optics, quantum computing, and particle physics. They are also used in the study of Bose-Einstein condensates and superconductivity. Their mathematical properties make them useful in a wide range of quantum mechanical systems.

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