Deducind thermodynamics from Quantum Physics and S>k

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How can deduced the four principles of thermodynamics from Quantum Physics and that the law that thermodynamics of a system is always greather than Boltzmann Constant K
 

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You really are going to have to restate your question.
and that the law that thermodynamics of a system is always greather than Boltzmann Constant K
Some of it just does not make any sense in English.
 

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