Determining the rate law from experimental data

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SUMMARY

The discussion centers on determining the rate law from experimental data using the initial rates method. Participants analyze the equation Rate2/Rate1=k2*[A]^m/k1*[A]^m to derive reaction orders. A specific issue arises when calculating the reaction order for reactant B, where conflicting results of -2.5 and -0.5 are obtained from different rate comparisons. The consensus is that the correct answer is -0.5, and the method requires consistent application of concentration ratios to ensure accurate results.

PREREQUISITES
  • Understanding of chemical kinetics and rate laws
  • Familiarity with the initial rates method
  • Knowledge of concentration units and their manipulation
  • Ability to interpret experimental data and equations
NEXT STEPS
  • Study the application of the initial rates method in detail
  • Learn how to derive rate laws from experimental data
  • Explore the concept of reaction order and its significance
  • Investigate common pitfalls in calculating reaction rates
USEFUL FOR

Chemistry students, educators, and researchers involved in experimental kinetics and those seeking to deepen their understanding of reaction mechanisms and rate laws.

fridakahlo
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Homework Statement


First question on PDF:
http://ars-chemia.net/Classes/102/Problem_Sets/Practice Exam for Exam 1 Key.pdf

Homework Equations


I used the initial rates method:
Rate2/Rate1=k2*[A]^m/k1*[A]^m

The Attempt at a Solution


When I solve these types of problems with the initial rates method, I get multiple possible solutions. For instance, for reactant B, I got -2.5 when comparing rates 3 and 2, but when comparing rates 3 and 1 I got -0.5. I know the answer is -0.5.
My question is how do I know which one is the most plausible answer when solving these types of problems?
 
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It was rather hard for me to make out what your question is. I guess it is about Question 1? This appears to be solved correctly, I presume the answers in red are yours? What is written above though does not correspond to this answer.
 
Last edited:
fridakahlo said:

Homework Statement


First question on PDF:
http://ars-chemia.net/Classes/102/Problem_Sets/Practice Exam for Exam 1 Key.pdf

Homework Equations


I used the initial rates method:
Rate2/Rate1=k2*[A]^m/k1*[A]^m

The Attempt at a Solution


When I solve these types of problems with the initial rates method, I get multiple possible solutions. For instance, for reactant B, I got -2.5 when comparing rates 3 and 2, but when comparing rates 3 and 1 I got -0.5. I know the answer is -0.5.
My question is how do I know which one is the most plausible answer when solving these types of problems?
you take any ratio ...answer should be same
If you take R1/R3 then [A] is canceled and if you do R3 and R1 then plug in the conc of A with raise to power of its order .. it should give us the same answer ...
 

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