Dielectric constant depression of water?

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SUMMARY

The discussion centers on the dielectric constant of water and its implications for coupling efficiency between quantum dots and wires. The user references a paper (doi:10.1103/PhysRevB.76.035420) that uses a dielectric constant of 2 for the surrounding medium, while noting that the cytoplasm of a cell has a dielectric constant around 50. The user seeks methods to suppress this dielectric constant, mentioning salt as a potential depressant and exploring the effects of supercritical water and freezing temperatures. The dielectric constant is also noted to vary with the frequency of electromagnetic radiation.

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  • Understanding of dielectric constants and their significance in quantum mechanics.
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  • Knowledge of the effects of temperature and phase changes on dielectric properties.
  • Basic principles of electromagnetic radiation and frequency dependence.
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  • Research the effects of salt concentration on the dielectric constant of water.
  • Investigate the properties of supercritical water and its applications in quantum systems.
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Researchers in quantum mechanics, materials scientists, and biophysicists focusing on the interactions between quantum dots and biological mediums, particularly those interested in optimizing coupling efficiency in high-dielectric environments.

excalibur313
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Hey Everyone. I am doing a project proposal where I am calculating the coupling efficiency between a quantum dot and a wire and I need to enter in values for the dielectric constant of the wire and the surrounding medium. I am working off a paper (doi:10.1103/PhysRevB.76.035420) where he uses the dielectric constant for the surrounding medium to be 2. I would like to do this in water (well actually the cytoplasm of a cell which I think is ~50) which has a much higher dielectric constant and unfortunately it seems to kill off the really efficient coupling that I was getting. Does anyone know of a way to suppress the dielectric constant and to somehow quantify how low I can get it? I know salt will depress it, but how much would I expect? I read that if I get water at a supercritical phase I can get it pretty low, but does anyone know of any other way? Thanks a lot for your help!
 
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Freezing will help, if you also drop the temperature below 0. Maybe that is what you mean by supercritical phase. Also, the dielectric constant is a function of the frequency of the EM radiation in question, and drops with increasing frequency.

Here is a quote off of the web: "The dielectric constant of ice at 0°C is virtually the same as that of water (88.0), but decreases rapidly with decreasing temperatures below 0°C, and with increasing frequency; by 0.1 MHz, kice ~ 2-4 with little influence of temperature." Source - http://www.nanomedicine.com/NMI/10.5.5.htm
 
I don;t think freezing is a good idea. It would solidify the medium and render the cells immobile
 

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