Difference Between Heat & Agitation - Atomic Scale

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SUMMARY

The discussion clarifies the distinction between agitation and heat at the atomic scale, particularly in the context of dissolving salt in water. Increasing the temperature of the water enhances the dissolution rate due to increased molecular movement, while agitation, such as stirring, facilitates diffusion by moving low concentration regions closer to the solute. The conversation references Joule's experiment, which demonstrated that mechanical work can convert to heat, establishing the Mechanical Equivalent of Heat, where 4.2 Joules of work produces one calorie of heat. This highlights the efficiency difference between agitation and thermal energy in influencing molecular interactions.

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CuriousBanker
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hello. Simple question here for somebody just learning the basics. On the atomic scale what’s the difference between agitation and heat? For example, diluting salt in water. If you increase the heat of the water, more salt dissolves. Stirring it also makes the salt dissolve more too it seems. But what’s the difference between stirring (agitation I’m guessing is what it’s called) and heat? Both are increased movement of molecules. So how come stirring the glass really fast with a spoon doesn’t Heat it up a lot?
 
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It's a matter of scale. Diffusion depends on the gradient of concentration and it is a random process and it will be faster as you increase the temperature but agitation will move regions of low concentration over the solute and that will increase the rate of diffusion near the salt. You have added a systematic element to the random movements in a stationary liquid.
 
CuriousBanker said:
So how come stirring the glass really fast with a spoon doesn’t Heat it up a lot?
It does. That is precisely the experiment that Joule did which showed the equivalence of work and heat. He showed that you could heat up a liquid by stirring it.
 
Dale said:
It does. That is precisely the experiment that Joule did which showed the equivalence of work and heat. He showed that you could heat up a liquid by stirring it.
It may be worth noting that the 'Mechanical Equivalent of Heat' that Joule found is that it takes 4.2 Joules of mechanical energy (work) to produce just one calorie of heat,
4.2 J corresponds to lifting 1kg by 0.42 m
1 calorie will raise the temperature of just 1gm of water by 1°C
A lot of Work for a very little Heat. :wink:
 

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