There are special cases when we can guess what the spectrum would be. For example, when the particle travels in the central field potential it can be shown that: when the energy [tex]E[/tex] of the particle is positive the spectrum is continuous and when [tex]E<0[/tex] the spectrum is discrete.
For example, if we have repulsive potential energy of the form [tex]U \sim 1/r[/tex], the total energy [tex]E[/tex] of the particle is positive. (Really,
[tex]E=\frac{1}{2m}\int {\psi^* \hat{\mathbf{P}}^2}\psi dV + \int {\psi^*U \psi}dV[/tex]
which is positive since [tex]U[/tex] is positive and the eigenvalues of [tex]\hat{\mathbf{P}}^2}[/tex] are positive numbers too).
So, in this potential field we have [tex]E>0[/tex] and continuous spectrum.
If [tex]U \sim -1/r[/tex] we have Сoulomb attraction and to possibilities: [tex]E>0[/tex] (continuous spectrum, ionized electron) and [tex]E<0[/tex] (discrete spectrum).
Finally, in case of 6-12 potential we have continuous spectrum for [tex]E>0[/tex] (dissociated molecule) and discrete spectrum for [tex]E<0[/tex].
Such examples show that we can guess what the spectrum is without doing anything with Schrödinger equation.